Skip to Content
MilliporeSigma

Skip To

232807

1,3-Dichloro-5,5-dimethylhydantoin

available chlorine 68 %

Synonym(s):

1,3-Dichloro-5,5-dimethyl-2,4-imidazolidinedione, DCDMH, NSC 33307, NSC 38630

Sign In to View Organizational & Contract Pricing.

Select a Size

Change View
Size/SKUAvailabilityPrice
250 g

Available to ship TODAY

$74.30
1 kg

Available to ship TODAY

$139.00

About This Item

Empirical Formula (Hill Notation):
C5H6Cl2N2O2
CAS Number:
Molecular Weight:
197.02
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
204-258-7
Beilstein/REAXYS Number:
146013
MDL number:
Form:
powder

$74.30


Available to ship TODAYDetails


​
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist


form

powder

Quality Segment

composition

available chlorine, 68%

mp

132-134 °C (lit.)

solubility

water: soluble 0.21% at 25 °C(lit.), carbon tetrachloride: freely soluble 12.5%(lit.), chloroform: freely soluble 14%(lit.), methylene chloride: freely soluble 30%(lit.), benzene: freely soluble 9.2%(lit.), chlorinated solvents: freely soluble at 25 °C(lit.)

SMILES string

CC1(C)N(Cl)C(=O)N(Cl)C1=O

InChI

1S/C5H6Cl2N2O2/c1-5(2)3(10)8(6)4(11)9(5)7/h1-2H3

InChI key

KEQGZUUPPQEDPF-UHFFFAOYSA-N

Application

1,3-Dichloro-5,5-dimethylhydantoin was used:
  • in reaction of chlorination of cytosine base
  • in the synthesis of α-chloroacetophenones
  • as an effective oxidizing agent for the oxidation of urazoles and bis-urazoles to their corresponding triazolinediones
Reagent involved in:
  • Microwave-assisted aromatization of trisubstituted pyrazolines
  • Asymmetric chlorolactonization chlorenium source
  • Oxidative chlorination for the synthesis of arenesulfonyl chlorides
  • Selective halogenation for the synthesis of halo ketones
  • Chlorination reactions

Compare Similar Items

View Full Comparison

Show Differences

1 of 1

This Item
D161403M49887D4505
description

available chlorine 68 %

description

97%

description

97%

description

≥99%

solubility

methylene chloride: freely soluble 30%(lit.), chloroform: freely soluble 14%(lit.), chlorinated solvents: freely soluble at 25 °C(lit.), benzene: freely soluble 9.2%(lit.), carbon tetrachloride: freely soluble 12.5%(lit.), water: soluble 0.21% at 25 °C(lit.)

solubility

-

solubility

-

solubility

aqueous base: soluble

Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

200

form

powder

form

crystals

form

-

form

powder

mp

132-134 °C (lit.)

mp

174-177 °C (lit.)

mp

156-157 °C (lit.)

mp

-

composition

available chlorine, 68%

composition

-

composition

-

composition

-


Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Ox. Sol. 2 - Skin Irrit. 2 - Skin Sens. 1

supp_hazards

Storage Class

5.1B - Oxidizing hazardous materials

WGK

WGK 2

Flash Point (°F)

345.2 °F

Flash Point (°C)

174 °C

PPE (personal protective equipment)

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges



Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

It looks like we've run into a problem, but you can still download Certificates of Analysis from our Documents section.

If you need assistance, please contact Customer Support

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library



Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

Reviews

No rating value

Active Filters