317519
Methyl 2-acetamidoacrylate
98%
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| Size/SKU | Availability | Price |
|---|---|---|
5 g | Available to ship TODAY | $318.00 |
About This Item
Linear Formula:
H2C=C(NHCOCH3)CO2CH3
CAS Number:
Molecular Weight:
143.14
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12162002
MDL number:
$318.00
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Quality Segment
assay
98%
bp
104 °C/8 mmHg (lit.)
mp
50-52 °C (lit.)
SMILES string
COC(=O)C(=C)NC(C)=O
InChI
1S/C6H9NO3/c1-4(6(9)10-3)7-5(2)8/h1H2,2-3H3,(H,7,8)
InChI key
SMWNFFKPVLVOQQ-UHFFFAOYSA-N
General description
Conjugated addition of secondary amines, imidazole and pyrazole to methyl 2 methyl 2-acetamidoacrylate in the presence of a catalyst results in the formation of β-Dialkylamino-α-alanine and β-(N-heteroaryl)-α-alanine derivatives. Methyl-2-acetamidoacrylate (M2AA) is an anti-inflammatory agent. The catalytic reaction of methyl 2-acetamidoacrylate with Grignard′s reagents affords α-amino esters. M2AA can form thermosensitive copolymers with methyl acrylate.
Application
Methyl 2-acetamidoacrylate can undergo [2+2] cycloaddition (Michael–Dieckmann-type reaction) with ketene diethyl acetal to yield the cyclobutane core. It may be used in rhodium-catalyzed 2-alkenylpyrrole formation.
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This Item | |
|---|---|
| description 98% | description ≥98.0% (T) |
| assay 98% | assay ≥98.0% (T) |
| bp 104 °C/8 mmHg (lit.) | bp - |
| mp 50-52 °C (lit.) | mp 77-79 °C (lit.) |
| Quality Level 100 | Quality Level 200 |
Methyl 2-acetamidoacrylate Sigma-Aldrich | - |
Signal Word
Warning
Hazard Codes
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
235.4 °F - closed cup
Flash Point (°C)
113 °C - closed cup
PPE (personal protective equipment)
dust mask type N95 (US), Eyeshields, Gloves
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