330744
Tetrapropylammonium perruthenate
97%
Synonym(s):
TPAP
Select a Size
| Size/SKU | Availability | Price |
|---|---|---|
250 mg | Check Cart for Availability | $84.80 |
1 g | Check Cart for Availability | $289.00 |
About This Item
$84.80
Quality Segment
assay
97%
form
solid
reaction suitability
core: ammonium, reaction type: phase-transfer, reagent type: oxidant
mp
~160 °C (dec.) (lit.)
functional group
amine
SMILES string
[O-][Ru](=O)(=O)=O.CCC[N+](CCC)(CCC)CCC
InChI
1S/C12H28N.4O.Ru/c1-5-9-13(10-6-2,11-7-3)12-8-4;;;;;/h5-12H2,1-4H3;;;;;/q+1;;;;-1;
InChI key
NQSIKKSFBQCBSI-UHFFFAOYSA-N
General description
Application
- For the conversion of sulfides to sulfones by oxidation reaction.
- In the isomerization of allylic alcohols into the corresponding saturated carbonyl derivatives.
- Along with N-methylmorpholine N-oxide (NMO) for the cleavage of glycol to carboxylic acids.
TPAP can also be used as an oxidizing reagent:
- For the oxidation of benzyl alcohol to benzaldehyde and steroidal alcohols to corresponding ketones.
- To convert N,N′-dihydroxyimidazolidines to nitronyl nitroxide free radicals.
- To oxidize hydroxyl-substituted tri-n-butylammonium trifluoroborates to aldehydes and ketones without concomitant cleavage of the carbon-boron bond.
1 of 1
This Item | |||
|---|---|---|---|
| description 97% | description - | description ≥98% | description 98% |
| assay 97% | assay - | assay ≥98% | assay 98% |
| Quality Level 200 | Quality Level 100 | Quality Level 200 | Quality Level 200 |
| reaction suitability reagent type: oxidant, core: ammonium | reaction suitability reagent type: oxidant, core: potassium | reaction suitability core: ammonium | reaction suitability core: ammonium |
| form solid | form solid | form solid | form powder |
| mp ~160 °C (dec.) (lit.) | mp - | mp 280-285 °C (dec.) (lit.) | mp 240-242 °C (lit.) |
| functional group amine | functional group - | functional group - | functional group - |
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
PPE (personal protective equipment)
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
Signal Word
Danger
Hazard Codes
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Ox. Sol. 2 - Skin Irrit. 2
Storage Class
5.1B - Oxidizing hazardous materials
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