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For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
337773
Chlorodiisopropylphosphine
96%, liquid
Sustainability features
Synonym(s):
Diisopropylphosphine chloride
Select a Size
| Size/SKU | Availability | Price |
|---|---|---|
5 g | Available to ship TODAY | $92.50 |
25 g | Available to ship TODAY | $263.00 |
About This Item
$92.50
Available to ship TODAYDetails
Product Name
Chlorodiisopropylphosphine, 96%
Quality Segment
assay
96%
form
liquid
reaction suitability
reagent type: ligand
reaction type: Arylations
greener alternative product characteristics
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product, Sustainability features
refractive index
n20/D 1.475 (lit.)
bp
69 °C/33 mmHg (lit.)
density
0.959 g/mL at 25 °C (lit.)
functional group
phosphine
greener alternative category
SMILES string
CC(C)P(Cl)C(C)C
InChI
1S/C6H14ClP/c1-5(2)8(7)6(3)4/h5-6H,1-4H3
InChI key
JZPDBTOWHLZQFC-UHFFFAOYSA-N
General description
Application
- To synthesize p-styryldiisopropylphosphine by reacting with 4-chlorostyrene via Grignard reaction.
- As a phosphination reagent in combination with [Cp2Zr(1-butene)(DMAP)] (Cp=cyclopentadienyl; DMAP= 4-(dimethylamino)pyridine)) for the zirconophosphination of alkynes to form zirconoalkenylphosphines.
- A luminescent mixed-donor platinum POCN pincer complex via cyclometalation process.
1 of 1
This Item | |||
|---|---|---|---|
| description 96% | description 96% | description 1.0 M in 2-methyltetrahydrofuran | description anhydrous, 99.8% |
| reaction suitability reagent type: ligand | reaction suitability reaction type: Stille Coupling, reaction type: Hiyama Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Negishi Coupling, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Sonogashira Coupling | reaction suitability reagent type: ligand | reaction suitability - |
| assay 96% | assay 96% | assay - | assay 99.8% |
| functional group phosphine | functional group phosphine | functional group phosphine | functional group - |
| form liquid | form liquid | form liquid | form liquid |
| Quality Level 100 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
| bp 69 °C/33 mmHg (lit.) | bp 320 °C (lit.) | bp - | bp 83 °C (lit.) |
Signal Word
Danger
Hazard Codes
Precautionary Statements
Hazard Classifications
Flam. Liq. 2 - Skin Corr. 1B
Storage Class
3 - Flammable liquids
WGK
WGK 3
Flash Point (°F)
39.2 °F - closed cup
Flash Point (°C)
4 °C - closed cup
PPE (personal protective equipment)
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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