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347191

Diethyl meso-2,5-dibromoadipate

98%

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5 g

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$46.70
$35.02
25 g

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$178.00

About This Item

Linear Formula:
[-CH2CH(Br)CO2C2H5]2
CAS Number:
Molecular Weight:
360.04
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
98%

$35.02

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Quality Segment

assay

98%

mp

65-67 °C (lit.)

functional group

bromo, ester

SMILES string

CCOC(=O)[C@@H](Br)CC[C@@H](Br)C(=O)OCC

InChI

1S/C10H16Br2O4/c1-3-15-9(13)7(11)5-6-8(12)10(14)16-4-2/h7-8H,3-6H2,1-2H3/t7-,8+

InChI key

UBCNJHBDCUBIPB-OCAPTIKFSA-N

General description

Diethyl meso-2,5-dibromoadipate reacts with N-methylallylamine in the presence of potassium carbonate to yield two diastereomers of diethyl 2-allyl-N-methylpyrrolidine-2,5-dicarboxylate.

Application

Diethyl meso-2,5-dibromoadipate may be employed as difunctional initiator during n-butyl acrylate (n-BuA) polymerization, leading to α,ω-bromo-poly(n-BuA) having narrow molecular weight distribution. It was also used:
  • as bifunctional atom transfer radical polymerization (ATRP) initiator
  • as initiator during the solution polymerization of octadecyl ester ether dimer by ATRP
  • in the synthesis of diethyl 2,5-diazidoadipate

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This Item
106550168017361461
description

98%

description

≥97%

description

99%

description

99%

assay

98%

assay

≥97%

assay

99%

assay

99%

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

200

mp

65-67 °C (lit.)

mp

241 °C (dec.) (lit.)

mp

200 °C (dec.) (lit.)

mp

32-34 °C (lit.)

functional group

ester, bromo

functional group

phenyl, bromo

functional group

carboxylic acid

functional group

hydroxyl


Pictograms

CorrosionExclamation mark

Signal Word

Danger

Hazard Codes

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

Target Organs

Respiratory system

Storage Class

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

PPE (personal protective equipment)

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges



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