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409170

Tributylgermanium hydride

99%

Synonym(s):

Tributylgermane

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Size/SKUAvailabilityPrice
1 g

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$215.00

About This Item

Linear Formula:
[CH3(CH2)3]3GeH
CAS Number:
Molecular Weight:
244.99
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:

$215.00


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Quality Segment

assay

99%

form

liquid

reaction suitability

core: germanium, reagent type: reductant

refractive index

n20/D 1.45 (lit.)

bp

123 °C/20 mmHg (lit.)

density

0.949 g/mL at 25 °C (lit.)

SMILES string

CCCC[GeH](CCCC)CCCC

InChI

1S/C12H28Ge/c1-4-7-10-13(11-8-5-2)12-9-6-3/h13H,4-12H2,1-3H3

InChI key

KTSWILXIWHVQLR-UHFFFAOYSA-N

General description

Tributylgermanium hydride is a radical generating reagent. Reductive alkylation of active olefins with alkyl halides with tributylgermanium hydride was investigated in detail.

Application

Efficient reducing agent for benzylic chlorides.

Packaging

Packaged in glass bottles

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This Item
86859192724214973
description

99%

description

≥99.0% (T)

description

25 wt. % in toluene

description

1.0 M in methylene chloride

assay

99%

assay

≥99.0% (T)

assay

-

assay

-

form

liquid

form

crystals or chunks

form

liquid

form

liquid

density

0.949 g/mL at 25 °C (lit.)

density

-

density

0.846 g/mL at 25 °C

density

1.23 g/mL at 25 °C

bp

123 °C/20 mmHg (lit.)

bp

-

bp

-

bp

-

refractive index

n20/D 1.45 (lit.)

refractive index

-

refractive index

-

refractive index

-

reaction suitability

core: germanium, reagent type: reductant

reaction suitability

core: ammonium

reaction suitability

reagent type: reductant

reaction suitability

reagent type: reductant


Pictograms

CorrosionExclamation mark

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1

Storage Class

10 - Combustible liquids

WGK

WGK 3

Flash Point (°F)

235.4 °F - closed cup

Flash Point (°C)

113 °C - closed cup

PPE (personal protective equipment)

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter



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