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412287

Pyromellitic dianhydride

97%

Synonym(s):

Benzene-1,2,4,5-tetracarboxylic dianhydride, PMDA

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Size/SKUAvailabilityPrice
100 g

Available to ship TODAY

$79.50
500 g

Available to ship TODAY

$254.00

About This Item

Empirical Formula (Hill Notation):
C10H2O6
CAS Number:
Molecular Weight:
218.12
UNSPSC Code:
12162002
NACRES:
NA.23
PubChem Substance ID:
EC Number:
201-898-9
Beilstein/REAXYS Number:
213583
MDL number:

$79.50


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Quality Segment

assay

97%

form

powder

bp

397-400 °C (lit.)

mp

283-286 °C (lit.)

SMILES string

O=C1OC(=O)c2cc3C(=O)OC(=O)c3cc12

InChI

1S/C10H2O6/c11-7-3-1-4-6(10(14)16-8(4)12)2-5(3)9(13)15-7/h1-2H

InChI key

ANSXAPJVJOKRDJ-UHFFFAOYSA-N

General description

Pyromellitic dianhydride is a dianhydride class of monomers commonly used in the preparation of polyimides polymers which are used in aerospace, electronics, and automotive industries because of their excellent thermal stability, high mechanical strength, and inherent flame resistance. It is also used in the synthesis of thermoplastic polymers such as polyesters and polyethers, as well as plasticizers and epoxy resins. Additionally, PMDA serves as a curing agent for epoxy resins. Epoxy resins are widely used in adhesives, coatings, composites, and electrical insulation materials.

Pyromellitic dianhydride (PMDA) is an acidic anhydride that can be used as a repair agent and as a chain extender in the formation of polyethylene terephthalate (PET) based chain extensions. It is mainly used in the production of thermoplastics and other coating applications.

Application

PMDA can be used as:
  • A monomer to synthesize aromatic polyimides with excellent thermo-mechanical and chemical properties. These polymers find the applications in automotive and electronic industries.
  • A capping agent in the development of siloxane-based hybrid materials for potential usage in organic electronics.
  • A monomer in the preparation and modification of thin film composite membranes, which are used in water purification, gas separation, and biomedical devices.
  • A monomer in the synthesis of pyromellitic diimide-based copolymers as stable cathode active materials for lithium and sodium-ion batteries.

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This Item
89748P73005902101
description

97%

description

analytical standard

description

97%

description

mixture of isomers, contains 1000-4000 ppm BHT as inhibitor

assay

97%

assay

≥98.0%

assay

97%

assay

-

mp

283-286 °C (lit.)

mp

283-286 °C (lit.)

mp

>320 °C (lit.)

mp

-

form

powder

form

-

form

powder

form

liquid

bp

397-400 °C (lit.)

bp

397-400 °C (lit.)

bp

-

bp

-

Quality Level

200

Quality Level

100

Quality Level

200

Quality Level

-


Pictograms

Health hazardCorrosion

Signal Word

Danger

Hazard Codes

Hazard Classifications

Eye Dam. 1 - Resp. Sens. 1 - Skin Sens. 1

Storage Class

11 - Combustible Solids

WGK

WGK 1

Flash Point (°F)

716.0 °F - closed cup

Flash Point (°C)

380 °C - closed cup

PPE (personal protective equipment)

dust mask type N95 (US), Eyeshields, Faceshields, Gloves



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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