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43162

2-(Diphenylphosphino)ethylamine

≥95.0% (GC), liquid

Sustainability features

Synonym(s):

(2-Aminoethyl)diphenylphosphine, 1-Amino-2-(diphenylphosphino)ethane

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Size/SKUAvailabilityPrice
1 g
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$194.00

About This Item

Empirical Formula (Hill Notation):
C14H16NP
CAS Number:
4848-43-5
Molecular Weight:
229.26
NACRES:
NA.22
PubChem Substance ID:
57650168
UNSPSC Code:
12352116
MDL number:
MFCD00233831
Beilstein/REAXYS Number:
644931

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Product Name

2-(Diphenylphosphino)ethylamine, ≥95.0% (GC)

Quality Segment

assay

≥95.0% (GC)

form

liquid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product, Sustainability features

functional group

phosphine

greener alternative category

SMILES string

NCCP(c1ccccc1)c2ccccc2

InChI

1S/C14H16NP/c15-11-12-16(13-7-3-1-4-8-13)14-9-5-2-6-10-14/h1-10H,11-12,15H2

InChI key

RXEPBCWNHKZECN-UHFFFAOYSA-N

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of the 12 Principles of Green Chemistry. This product features an advanced catalyst system with unique mechanistic properties and broad substrate scope, enabling efficient transformations across diverse chemical structures. By expanding reaction versatility while reducing waste and byproduct formation, this catalyst simplifies synthesis workflows and minimizes environmental impact. Click here for more information.
2-(Diphenylphosphino)ethylamine is a phosphine ligand that has a bidentate structure with the phosphorus atom donating two lone pair electrons to coordinate with metal atoms. It is used as a reactant to synthesize active catalyst for the selective hydrogenation of amides. In addition, it is also used as a precursor to synthesize other phosphine ligands.

Application

2-(Diphenylphosphino)ethylamine can be used as a bidentate ligand in the nickel catalyst system for the reductive [2+2] cycloaddition reaction to synthesize cyclobutenes from alkynes.

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2-(Diphenylphosphino)ethylamine ≥95.0% (GC)

Sigma-Aldrich

43162

2-(Diphenylphosphino)ethylamine

(S)-1-(Diphenylphosphino)-3-methyl-2-butylamine 97%

Sigma-Aldrich

748277

(S)-1-(Diphenylphosphino)-3-methyl-2-butylamine

cis-1,2-Bis(diphenylphosphino)ethylene 97%

Sigma-Aldrich

327646

cis-1,2-Bis(diphenylphosphino)ethylene

Ethylenebis(diphenylphosphine) 99%

Sigma-Aldrich

376728

Ethylenebis(diphenylphosphine)

description

≥95.0% (GC)

description

97%

description

97%

description

99%

assay

≥95.0% (GC)

assay

97%

assay

97%

assay

99%

reaction suitability

reaction type: Negishi Coupling, reaction type: Hiyama Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: Stille Coupling, reaction type: Heck Reaction, reagent type: ligand, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Sonogashira Coupling

reaction suitability

reaction type: Hiyama Coupling, reagent type: ligand, reaction type: Negishi Coupling, reaction type: Stille Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Suzuki-Miyaura Coupling, reaction type: Sonogashira Coupling, reaction type: Heck Reaction

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Negishi Coupling, reaction type: Stille Coupling, reaction type: Hiyama Coupling, reaction type: Heck Reaction, reaction type: Sonogashira Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand

reaction suitability

reagent type: ligand, reaction type: Suzuki-Miyaura Coupling, reaction type: Heck Reaction, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Stille Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Hiyama Coupling

form

liquid

form

liquid

form

-

form

-

functional group

phosphine

functional group

phosphine

functional group

phosphine

functional group

phosphine

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

200

sustainability

Greener Alternative Product

sustainability

-

sustainability

Greener Alternative Product

sustainability

-

Pictograms

Corrosion
GHS05

Signal Word

Danger

Hazard Codes

H314

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

PPE (personal protective equipment)

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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