457701
(S)-(−)-2-Methyl-CBS-oxazaborolidine solution
1 M in toluene
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Synonym(s):
α,α-Diphenyl-L-prolinol methylboronic acid cycl-amide ester, (S)-1-Methyl-3,3-diphenyl-tetrahydro-pyrrolo[1,2c][1,3,2]oxazaborole, (S)-3,3-Diphenyl-1-methyltetrahydro-3H-pyrrolo[1,2-c][1,3,2]oxazaborole, (S)-Tetrahydro-1-methyl-3,3-diphenyl-1H,3H-pyrrolo[1,2-c][1,3,2]oxazaborole
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| Size/SKU | Availability | Price |
|---|---|---|
5 mL | Check Cart for Availability | $116.00 |
25 mL | Check Cart for Availability | $396.00 |
About This Item
Quality Segment
concentration
1 M in toluene
bp
111 °C
density
0.929 g/mL at 25 °C
functional group
phenyl
storage temp.
room temp
SMILES string
CB1OC([C@@H]2CCCN12)(c3ccccc3)c4ccccc4
InChI
1S/C18H20BNO/c1-19-20-14-8-13-17(20)18(21-19,15-9-4-2-5-10-15)16-11-6-3-7-12-16/h2-7,9-12,17H,8,13-14H2,1H3/t17-/m0/s1
InChI key
VMKAFJQFKBASMU-KRWDZBQOSA-N
Application
It may also be used in the preparation of:
- (1S)-2-azido-1-(2,2-dimethyl-4H-1,3-benzodioxin-6-yl)ethanol
- (R)-α-deuteriobenzyl alcohol
- (R)-2-(1-hydroxyethyl)benzo[b]thiophene
Other Notes
1 of 1
This Item | |||
|---|---|---|---|
| description 1 M in toluene | description 1 M in THF | description ≥95% | description 98%, optical purity ee: 99% (HPLC) |
| functional group phenyl | functional group phenyl | functional group phenyl | functional group phenyl, hydroxyl, amine |
| Quality Level 100 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
| storage temp. room temp | storage temp. - | storage temp. - | storage temp. - |
| density 0.929 g/mL at 25 °C | density 0.942 g/mL at 25 °C | density - | density - |
| bp 111 °C | bp - | bp - | bp - |
| concentration 1 M in toluene | concentration 1 M in THF | concentration - | concentration - |
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Signal Word
Danger
Hazard Codes
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 2 - STOT SE 3
Target Organs
Central nervous system
Storage Class
3 - Flammable liquids
WGK
WGK 3
Flash Point (°F)
39.2 °F - closed cup
Flash Point (°C)
4 °C - closed cup
PPE (personal protective equipment)
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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