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498041

Cyclopentylzinc bromide solution

0.5 M in THF

Synonym(s):

Bromo(cyclopentyl)zinc, Bromocyclopentylzinc

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Size/SKUAvailabilityPrice
50 mL
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$383.00

About This Item

Linear Formula:
C5H9ZnBr
CAS Number:
Molecular Weight:
214.42
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:

$383.00


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Quality Segment

concentration

0.5 M in THF

density

0.955 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

Br[Zn]C1CCCC1

InChI

1S/C5H9.BrH.Zn/c1-2-4-5-3-1;;/h1H,2-5H2;1H;/q;;+1/p-1

InChI key

GOPYCBPMCCJYSN-UHFFFAOYSA-M

Application

Cyclopentylzinc bromide is an organozinc reagent that can be used in:
  • The synthesis of polyfunctional indoles by reacting with various aryldiazonium salts via Fischer indole synthesis.
  • Negishi cross-coupling reactions with various haloarenes in presence of Pd-complex catalyst.
  • The preparation of aryl alkyl ketones by alkylation of aryl N-methyl-N-tosyl or N-benzyl-N-(tert-butoxycarbonyl) amide derivatives in the presence of Ni catalyst and imidazolidinylidene ligand.

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

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description

0.5 M in THF

description

0.5 M in THF

description

0.5 M in THF

description

0.5 M in THF

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

density

0.955 g/mL at 25 °C

density

0.99 g/mL at 25 °C

density

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density

0.992 g/mL at 25 °C

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

2-8°C

concentration

0.5 M in THF

concentration

0.5 M in THF

concentration

0.5 M in THF

concentration

0.5 M in THF


Signal Word

Danger

supp_hazards

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

Flash Point (°F)

1.4 °F - closed cup

Flash Point (°C)

-17 °C - closed cup

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3 - Water-react. 2

Target Organs

Central nervous system, Respiratory system



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