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656763

Di-μ-chlorotetraethylene dirhodium(I)

solid

Synonym(s):

Bis[chlorobis(ethylene)rhodium], Bis[chlorodiethylenerhodium], Chlorobis(ethylene)rhodium dimer, Dichlorotetra(ethene)dirhodium, Dichlorotetrakis(ethene)dirhodium, Diethylenerhodium chloride dimer, Divinylrhodium chloride dimer, Tetrakis(ethylene)dichlorodirhodium, [Rh(C2H4)2Cl]2

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Size/SKUAvailabilityPrice
100 mg
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$137.00
1 g
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$757.00

About This Item

Empirical Formula (Hill Notation):
C8H16Cl2Rh2
CAS Number:
Molecular Weight:
388.93
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
235-145-0
MDL number:

$137.00


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Product Name

Di-μ-chlorotetraethylene dirhodium(I),

form

solid

Quality Segment

reaction suitability

reagent type: catalyst, reagent type: catalyst
core: rhodium

storage temp.

−20°C

SMILES string

Cl[Rh].Cl[Rh].C=C.C=C.C=C.C=C

InChI

1S/4C2H4.2ClH.2Rh/c4*1-2;;;;/h4*1-2H2;2*1H;;/q;;;;;;2*+1/p-2

InChI key

OOQJCPOXJFCGCR-UHFFFAOYSA-L

Application

Di-μ-chlorotetraethylene dirhodium(I) may be used in the preparation of Π-bound rhodium organometallic complexes of ROMP-derived poly(1,5-cyclooctadiene) (poly(COD)). [ROMP= Ring-Opening Metathesis Polymerization; COD= 1,5-cyclooctadiene]
Precursor to Rh(I) norbornadiene catalyst used in an asymmetric 1,4-addition of arylboronic acids to cyclic enones.

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This Item
701211249939686891
description

-

description

95%

description

96%

description

Umicore

reaction suitability

reagent type: catalyst, reagent type: catalyst
core: rhodium

reaction suitability

core: rhodium, reagent type: catalyst

reaction suitability

reagent type: catalyst, core: rhodium

reaction suitability

reaction type: Cross Couplings, reagent type: catalyst
reaction type: C-H Activation, core: rhodium

form

solid

form

solid

form

powder

form

powder

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

storage temp.

−20°C

storage temp.

2-8°C

storage temp.

-

storage temp.

-


pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Eye Irrit. 2

Storage Class

11 - Combustible Solids

wgk

WGK 3

ppe

Eyeshields, Gloves, type N95 (US)



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