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668192

(S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a;3,4- a′]dinaphthalen-4-yl)dimethylamine

97%

Synonym(s):

(S)-MonoPhos®

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1 g
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$69.10

About This Item

Empirical Formula (Hill Notation):
C22H18NO2P
CAS Number:
185449-80-3
Molecular Weight:
359.36
UNSPSC Code:
12352005
PubChem Substance ID:
24884967
NACRES:
NA.22
MDL number:
MFCD03426988

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Quality Segment

assay

97%

form

solid

reaction suitability

reagent type: chrial catalyst

mp

190 °C (dec.)

functional group

amine

SMILES string

[p]1([o]c2c(c4c([o]1)ccc5c4cccc5)c3c(cc2)cccc3)N(C)C

InChI

1S/C22H18NO2P/c1-23(2)26-24-19-13-11-15-7-3-5-9-17(15)21(19)22-18-10-6-4-8-16(18)12-14-20(22)25-26/h3-14H,1-2H3

InChI key

QCHAVHXSBZARBO-UHFFFAOYSA-N

Application

DSM MonoPhos Family of Highly Efficient Privileged Ligands

Legal Information

Sold under license from DSM for research purposes only.
MonoPhos is a registered trademark of DSM IP Assets B.V.

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This Item
665363665290665355
(S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a;3,4- a′]dinaphthalen-4-yl)dimethylamine 97%

Sigma-Aldrich

668192

(S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a;3,4- a′]dinaphthalen-4-yl)dimethylamine

(S,R,R)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a′]dinaphthalen-4-yl)bis(1-phenylethyl)amine 95% (HPLC)

Sigma-Aldrich

665363

(S,R,R)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a′]dinaphthalen-4-yl)bis(1-phenylethyl)amine

(S,S,S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a’]dinaphthalen-4-yl)bis(1-phenylethyl)amine 97%

Sigma-Aldrich

665290

(S,S,S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a′]dinaphthalen-4-yl)bis(1-phenylethyl)amine

(S)-(+)-Benzyl(3,5-dioxa-4-phospha-cyclohepta[2,1-a;3,4-a′]dinaphthalen-4-yl)methylamine 97%

Sigma-Aldrich

665355

(S)-(+)-Benzyl(3,5-dioxa-4-phospha-cyclohepta[2,1-a;3,4-a′]dinaphthalen-4-yl)methylamine

description

97%

description

95% (HPLC)

description

97%

description

97%

assay

97%

assay

95% (HPLC)

assay

97%

assay

97%

functional group

amine

functional group

amine, phenyl

functional group

amine, phenyl

functional group

-

form

solid

form

-

form

solid

form

solid

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

mp

190 °C (dec.)

mp

102-103 °C

mp

88-89 °C

mp

155-159 °C

(S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a;3,4-a′]dinaphthalen-4-yl)dimethylamine

laboratory-grade (S,R,R)-(+)-3,5-Dioxa-4-phosphacyclohepta ligand, reagent for diethylzinc mediated allylation, CAS 497883-22-4 chiral ligand, high enantioselectivity (S,R,R)-(+)-3,5-Dioxa-4-phosphacyclohepta, phosphoramidite ligand for Michael acceptors, asymmetric synthesis with (S,R,R)-(+)-3,5-Dioxa-4-phosphacyclohepta, (S,R,R)-(+)-3,5-Dioxa-4-phosphacyclohepta dinaphthalen-4-yl bis(1-phenylethyl)amine, chiral phosphoramidite ligand for copper-catalyzed reactions, palladium-catalyzed reactions with (S,R,R)-(+)-3,5-Dioxa-4-phosphacyclohepta, Sigma-Aldrich (S,R,R)-(+)-3,5-Dioxa-4-phosphacyclohepta ligand, 1-phenylethyl amine chiral phosphoramidite, MonoPhos ligands for asymmetric synthesis, N,N-Bis[(1R)-1-phenylethyl]-dinaphtho ligand, enantioselective synthesis (S,R,R)-(+)-3,5-Dioxa-4-phosphacyclohepta

-

-

Storage Class

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

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