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683345

[Pd2(dba)3] x dba

Umicore, powder

Synonym(s):

Tris(dibenzylideneacetone)dipalladium(0), Pd2dba3, Pd2(dba)3

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Size/SKUAvailabilityPrice
500 mg

Available to ship TODAYfromMILWAUKEE

$61.40
5 g

Available to ship TODAYfromMILWAUKEE

$448.00
50 g

Available to ship TODAYfromMILWAUKEE

$2,250.00

About This Item

Linear Formula:
(C6H5CH=CHCOCH=CHC6H5)3Pd2
CAS Number:
Molecular Weight:
915.72
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:

$61.40


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Product Name

[Pd2(dba)3] x dba, Umicore

Quality Segment

form

powder

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

mp

152-155 °C (lit.)

storage temp.

2-8°C

SMILES string

[Pd].[Pd].O=C(\C=C\c1ccccc1)/C=C/c2ccccc2.O=C(\C=C\c3ccccc3)/C=C/c4ccccc4.O=C(\C=C\c5ccccc5)/C=C/c6ccccc6

InChI

1S/3C17H14O.2Pd/c3*18-17(13-11-15-7-3-1-4-8-15)14-12-16-9-5-2-6-10-16;;/h3*1-14H;;/b3*13-11+,14-12+;;

InChI key

CYPYTURSJDMMMP-WVCUSYJESA-N

Application

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis

Catalyst for C-C and C-N bond formation especially Suzuki, Heck coupling reaction

Legal Information

Product of Umicore

Additional information available at www.pmc.umicore.com

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This Item
328774919772366315
description

Umicore

description

97%

description

-

description

-

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Negishi Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: Stille Coupling, reaction type: Heck Reaction, core: palladium, reaction type: Hiyama Coupling, reaction type: Sonogashira Coupling, reaction type: Cross Couplings, reagent type: catalyst

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Stille Coupling, reaction type: Hiyama Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: Negishi Coupling, core: palladium, reaction type: Heck Reaction, reaction type: Sonogashira Coupling, reagent type: catalyst

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

reaction suitability

reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Suzuki-Miyaura Coupling, core: palladium, reaction type: Stille Coupling, reaction type: Cross Couplings, reagent type: catalyst

form

powder

form

powder

form

solid

form

solid

Quality Level

200

Quality Level

200

Quality Level

100

Quality Level

100

storage temp.

2-8°C

storage temp.

-

storage temp.

2-8°C

storage temp.

-

mp

152-155 °C (lit.)

mp

152-155 °C (lit.)

mp

-

mp

131-135 °C (lit.)


Pictograms

Exclamation markEnvironment

Signal Word

Warning

Hazard Codes

Hazard Classifications

Aquatic Chronic 2 - Skin Sens. 1

Storage Class

11 - Combustible Solids

WGK

WGK 2

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

PPE (personal protective equipment)

Eyeshields, Gloves, type N95 (US)



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

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