Skip to Content
MilliporeSigma

Key Documents

View All Documentation

Skip To

692301

RuCl2[(R)−DM−BINAP][(R,R)−DPEN]

Synonym(s):

Dichloro[(R)−2,2′−bis[di(3,5−xylyl)phosphino]−1,1′−binaphthyl][(1R,2R)−1,2−diphenylethylenediamine]ruthenium(II)

Sign In to View Organizational & Contract Pricing.

Select a Size

Change View
Size/SKUAvailabilityPrice
50 mg
Check Cart for Availability
$38.70

About This Item

Empirical Formula (Hill Notation):
C66H64Cl2N2P2Ru
CAS Number:
220114-38-5
Molecular Weight:
1119.15
NACRES:
NA.22
PubChem Substance ID:
329761481
UNSPSC Code:
12352005
MDL number:
MFCD09753028

$38.70

Check Cart for Availability
​
Request a Custom Order
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist

form

powder

Quality Segment

reaction suitability

reagent type: chrial catalyst
core: ruthenium
reaction type: Noyori Asymmetric Hydrogenation

functional group

amine, phenyl, phosphine

storage temp.

2-8°C

SMILES string

Cl[Ru]Cl.N[C@@H]([C@H](N)c1ccccc1)c2ccccc2.Cc3cc(C)cc(c3)P(c4cc(C)cc(C)c4)c5ccc6ccccc6c5-c7c(ccc8ccccc78)P(c9cc(C)cc(C)c9)c%10cc(C)cc(C)c%10

InChI

1S/C52H48P2.C14H16N2.2ClH.Ru/c1-33-21-34(2)26-43(25-33)53(44-27-35(3)22-36(4)28-44)49-19-17-41-13-9-11-15-47(41)51(49)52-48-16-12-10-14-42(48)18-20-50(52)54(45-29-37(5)23-38(6)30-45)46-31-39(7)24-40(8)32-46;15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12;;;/h9-32H,1-8H3;1-10,13-14H,15-16H2;2*1H;/q;;;;+2/p-2/t;13-,14-;;;/m.1.../s1

InChI key

HYMSONXJNGZZBM-ODQAEMFESA-L

General description

The product is a bis-naphthalene containing phosphine ligand, in conjugation with a ruthenium complex.

Application

RuCl2[(R)-DM-BINAP][(R,R)-DPEN] can catalyze the enantioselective asymmetric reduction of benzils to form the corresponding chiral 1,2-diols.
Takasago Ligands and Complexes for Asymmetric Reactions

Legal Information

Sold in collaboration with Takasago for research purposes only. JP Registration No. 2041996, 2731377, 2935453 JP Application No. 19970359654

Compare Similar Items

View Full Comparison

Show Differences

1 of 1

This Item
692255692409703907
RuCl2[(R)−DM−BINAP][(R,R)−DPEN]

Sigma-Aldrich

692301

RuCl2[(R)−DM−BINAP][(R,R)−DPEN]

RuCl2[(R)−DM−BINAP][(R)−DAIPEN]

Sigma-Aldrich

692255

RuCl2[(R)−DM−BINAP][(R)−DAIPEN]

(R)−RuCl[(p−cymene)(DM−BINAP)]Cl

Sigma-Aldrich

692409

(R)−RuCl[(p−cymene)(DM−BINAP)]Cl

RuCl(p-cymene)[(R,R)-Ts-DPEN]

Sigma-Aldrich

703907

RuCl(p-cymene)[(R,R)-Ts-DPEN]

description

-

description

-

description

-

description

-

reaction suitability

reagent type: catalyst
core: ruthenium
reaction type: Noyori Asymmetric Hydrogenation

reaction suitability

reagent type: catalyst
core: ruthenium
reaction type: Noyori Asymmetric Hydrogenation

reaction suitability

reagent type: catalyst
core: ruthenium
reaction type: Noyori Asymmetric Hydrogenation

reaction suitability

reagent type: catalyst
core: ruthenium
reaction type: Noyori Asymmetric Hydrogenation

form

powder

form

powder

form

powder

form

powder

functional group

amine, phosphine, phenyl

functional group

-

functional group

-

functional group

amine, phenyl

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

2-8°C

Dichloro ruthenium catalyst for organic synthesis

lab-grade RuCl2[(R)-DM-BINAP] for enantioselective reactions, Ruthenium-based catalyst for enantioselective ketone hydrogenation, 220114-32-9 Ruthenium(II) catalyst for asymmetric hydrogenation, RuCl2[(R)-DM-BINAP] for ketone hydrogenation, Ruthenium(II) dichloride catalyst for ketone reduction, RuCl2[(R)-DM-BINAP] for laboratories, Ruthenium(II) catalyst for Noyori-type ketone hydrogenation, Dichloro[(R)-DM-BINAP] Ruthenium(II) for asymmetric synthesis, Ruthenium catalyst for enantioselective ketone hydrogenation, high purity RuCl2[(R)-DM-BINAP] for research, RuCl2[(R)-DM-BINAP] catalyst, Dichloro[(R)-2,2′-bis[di(3,5-xylyl)phosphino]-1,1′-binaphthyl] ruthenium(II)

-

-

Storage Class

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

It looks like we've run into a problem, but you can still download Certificates of Analysis from our Documents section.

If you need assistance, please contact Customer Support

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Questions

Reviews

No rating value

Active Filters