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718165

Trioctylphosphine

97%, liquid

Sustainability features

Synonym(s):

TOP, P(Oct)3

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Size/SKUAvailabilityPrice
100 mL

Available to ship TODAYfromMILWAUKEE

$159.00
500 mL

Available to ship TODAY

$759.00
2 L

Available to ship TODAY

$1,930.00

About This Item

Linear Formula:
[CH3(CH2)7]3P
CAS Number:
Molecular Weight:
370.64
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352001
EC Number:
225-234-2
MDL number:
Beilstein/REAXYS Number:
1776995

$159.00


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Product Name

Trioctylphosphine, 97%

Quality Segment

assay

97%

form

liquid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand

sustainability

Sustainability features

refractive index

n20/D 1.468 (lit.)

bp

284-291 °C/50 mmHg (lit.)

density

0.831 g/mL at 25 °C (lit.)

functional group

phosphine

greener alternative category

SMILES string

CCCCCCCCP(CCCCCCCC)CCCCCCCC

InChI

1S/C24H51P/c1-4-7-10-13-16-19-22-25(23-20-17-14-11-8-5-2)24-21-18-15-12-9-6-3/h4-24H2,1-3H3

InChI key

RMZAYIKUYWXQPB-UHFFFAOYSA-N

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of the 12 Principles of Green Chemistry. This ligand enables size-controlled synthesis of metal phosphide nanocrystals and quantum dots with uniform morphology. Its use in low-temperature synthesis minimizes energy requirements and enables reproducible nanomaterial production. Click here for more information.
Trioctylphosphine serves as a phosphorus source and used in the synthesis of metal nanoparticles.

Application

Trioctylphosphine can be used for the conversion of metal nanocrystals, bulk powders, foils, wires, thin films to metal phosphides. It can also act as a solvent and stabilizer for synthesizing cadmium sulfide nanorods from cadmium acetate and sulfur.

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This Item
117854W280607
description

97%

description

technical grade, 90%

description

≥98%, FCC, FG

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: ligand, reaction type: Suzuki-Miyaura Coupling, reaction type: Hiyama Coupling, reaction type: Stille Coupling, reaction type: Negishi Coupling, reaction type: Heck Reaction, reaction type: Sonogashira Coupling

reaction suitability

reaction type: Stille Coupling, reaction type: Negishi Coupling, reaction type: Hiyama Coupling, reagent type: ligand, reaction type: Heck Reaction, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Suzuki-Miyaura Coupling, reaction type: Sonogashira Coupling

reaction suitability

-

assay

97%

assay

90%

assay

≥98%

form

liquid

form

-

form

-

functional group

phosphine

functional group

phosphine

functional group

-

Quality Level

100

Quality Level

-

Quality Level

400, 300

density

0.831 g/mL at 25 °C (lit.)

density

0.831 g/mL at 25 °C (lit.)

density

0.867 g/mL at 25 °C (lit.)


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Pictograms

Corrosion

Signal Word

Danger

Hazard Codes

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

Flash Point (°F)

296.6 °F - closed cup

Flash Point (°C)

147 °C - closed cup



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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