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764183

APhos Pd G3

97%, solid

Sustainability features

Synonym(s):

APhos-Pd-G3, Palladium G3-(4-(N,N-Dimethylamino)phenyl)di-tert-butylphosphine, [4-(Di-tert-butylphosphino)-N,N-dimethylaniline-2-(2′-aminobiphenyl)]palladium(II) methanesulfonate

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Size/SKUAvailabilityPrice
250 mg
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$81.50
1 g
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$200.00
5 g
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$731.00

About This Item

Empirical Formula (Hill Notation):
C29H41N2O3PPdS
CAS Number:
Molecular Weight:
635.11
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:

$81.50


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Product Name

APhos Pd G3, 97%

Quality Segment

product line

Buchwald precatalyst Generation 3

assay

97%

form

solid

feature

generation 3

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplings

greener alternative product score

old score: 5
new score: 3
Find out more about DOZN™ Scoring

sustainability

Sustainability features

mp

192-201 °C (decomposition)

functional group

phosphine

greener alternative category

SMILES string

NC1=C(C=CC=C1)C2=C([Pd]OS(C)(=O)=O)C=CC=C2.CN(C)C3=CC=C(C=C3)P(C(C)(C)C)C(C)(C)C

InChI

1S/C16H28NP.C12H10N.CH4O3S.Pd/c1-15(2,3)18(16(4,5)6)14-11-9-13(10-12-14)17(7)8;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h9-12H,1-8H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1

InChI key

SNUBBUQVCDWEAV-UHFFFAOYSA-M

General description

This product shows key improvements in Green Chemistry Principles “Waste Prevention”, “Atom Economy” and “Less Hazardous Chemical Synthesis”. Click here to view its DOZN scorecard.

Application

APhos Pd G3 is a Buchwald precatalyst that can be used in cross-coupling reactions.

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This Item
936820764299900608
description

97%

description

-

description

-

description

95%

reaction suitability

reaction type: Heck Reaction, reaction type: Sonogashira Coupling, core: palladium, reaction type: Negishi Coupling, reagent type: catalyst
reaction type: Cross Couplings, reaction type: Stille Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Suzuki-Miyaura Coupling, reaction type: Hiyama Coupling

reaction suitability

reaction type: Sonogashira Coupling, reaction type: Hiyama Coupling, reagent type: catalyst, reaction type: Suzuki-Miyaura Coupling, reaction type: Negishi Coupling, reaction type: Stille Coupling, reaction type: Heck Reaction, reaction type: Cross Couplings, reaction type: Buchwald-Hartwig Cross Coupling Reaction

reaction suitability

reaction type: Suzuki-Miyaura Coupling, core: palladium, reaction type: Hiyama Coupling, reagent type: catalyst
reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Negishi Coupling, reaction type: Stille Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Sonogashira Coupling

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: catalyst
reaction type: Cross Couplings

assay

97%

assay

-

assay

-

assay

95%

functional group

phosphine

functional group

-

functional group

phosphine

functional group

-

form

solid

form

solid

form

solid

form

powder or crystals

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

mp

192-201 °C (decomposition)

mp

-

mp

-

mp

204 °C


Storage Class

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable



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