798320
2-Bromo-6-(trimethylsilyl)phenyl triflate
95%
Synonym(s):
Garg 3-Bromobenzyne Precursor
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| Size/SKU | Availability | Price |
|---|---|---|
250 mg | Available to ship TODAYfromMILWAUKEE | $320.00 $332.00 |
1 g | Available to ship TODAYfromMILWAUKEE | $746.00 $559.50 |
About This Item
Empirical Formula (Hill Notation):
C10H12BrF3O3SSi
CAS Number:
Molecular Weight:
377.25
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Assay:
95%
Form:
liquid
Quality Segment
assay
95%
form
liquid
refractive index
n/D 1.492
density
1.482 g/L at 25 °C
functional group
bromo, fluoro, triflate
storage temp.
2-8°C
SMILES string
O=S(OC1=C([Si](C)(C)C)C=CC=C1Br)(C(F)(F)F)=O
InChI
1S/C10H12BrF3O3SSi/c1-19(2,3)8-6-4-5-7(11)9(8)17-18(15,16)10(12,13)14/h4-6H,1-3H3
InChI key
ZNKAHJCGEPVEBA-UHFFFAOYSA-N
Application
Synchronous Ar-F and Ar-Sn Bond Formation Through Fluorostannylation of Arynes
Continuous-Flow Synthesis of Trimethylsilylphenyl Perfluorosulfonate Benzyne Precursors
Continuous-Flow Synthesis of Trimethylsilylphenyl Perfluorosulfonate Benzyne Precursors
Bromosilyltriflate has been shown to be a useful precursor for the generation of a bromobenzyne intermediate. The bromobenzyne intermediate can be generated in the presence of cesium or potassium fluoride and can be trapped with various dipolariphiles.
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This Item | |||
|---|---|---|---|
| description 95% | description 95% | description 97% | description 98% |
| assay 95% | assay 95% | assay 97% | assay 98% |
| Quality Level 100 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
| refractive index n/D 1.492 | refractive index n/D 1.454 | refractive index - | refractive index - |
| density 1.482 g/L at 25 °C | density 1.266 at 25 °C | density - | density - |
| storage temp. 2-8°C | storage temp. 2-8°C | storage temp. - | storage temp. - |
| form liquid | form liquid | form crystals | form solid |
Signal Word
Danger
Hazard Codes
Precautionary Statements
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
Storage Class
8A - Combustible corrosive hazardous materials
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
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