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903124

(Ad−BippyPhos)2PdCl2

powder or crystals

Synonym(s):

Bis[5-(di(1-adamantyl)phosphino)-1′,3′,5′-triphenyl-1′H-[1,4′]bipyrazole] palladium(II) dichloride

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Size/SKUAvailabilityPrice
100 mg
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$298.00
250 mg
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$481.00

About This Item

Empirical Formula (Hill Notation):
C88H94N8P2PdCl2
CAS Number:
Molecular Weight:
1503.02
UNSPSC Code:
12161600
NACRES:
NA.22

$298.00


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Product Name

(Ad−BippyPhos)2PdCl2,

form

powder or crystals

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplings

mp

263 °C (Decomp)

functional group

phosphine

SMILES string

[Cl-][Pd+2]([Cl-])([P](C1=CC=NN1C=2C(=NN(C=3C=CC=CC3)C2C=4C=CC=CC4)C=5C=CC=CC5)(C67CC8CC(CC(C8)C6)C7)C9%10CC%11CC(CC(C%11)C9)C%10)[P](C%12=CC=NN%12C=%13C(=NN(C=%14C=CC=CC%14)C%13C=%15C=CC=CC%15)C=%16C=CC=CC%16)(C%17%18CC%19CC(CC(C%19)C%17)C%18)C%20%21CC%22CC(CC(C%22)C%20)C%21

InChI

InChI=1S/2C44H47N4P.2ClH.Pd/c2*1-4-10-36(11-5-1)40-42(41(37-12-6-2-7-13-37)47(46-40)38-14-8-3-9-15-38)48-39(16-17-45-48)49(43-24-30-18-31(25-43)20-32(19-30)26-43)44-27-33-21-34(28-44)23-35(22-33)29-44;;;/h2*1-17,30-35H,18-29H2;2*1H;/q;;;;+2/p-2

InChI key

CPOXOXXPPDSPGW-UHFFFAOYSA-L

Application

A Pd based catalyst with bulky ligand applicable to various cross-coupling reactions.

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description

-

description

95%

description

98%

description

98%, 1:1 MTBE adduct

reaction suitability

reaction type: Stille Coupling, core: palladium, reagent type: catalyst
reaction type: Cross Couplings, reaction type: Hiyama Coupling, reaction type: Sonogashira Coupling, reaction type: Negishi Coupling, reaction type: Heck Reaction, reaction type: Suzuki-Miyaura Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction

reaction suitability

reaction type: Negishi Coupling, core: palladium, reaction type: Stille Coupling, reaction type: Sonogashira Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reagent type: catalyst
reaction type: Cross Couplings, reaction type: Buchwald-Hartwig Cross Coupling Reaction

reaction suitability

reaction type: Hiyama Coupling, reaction type: Heck Reaction, reaction type: Stille Coupling, reagent type: catalyst
reaction type: Cross Couplings, reaction type: Suzuki-Miyaura Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling

reaction suitability

core: palladium, reaction type: Heck Reaction, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: catalyst
reaction type: Cross Couplings, reaction type: Hiyama Coupling, reaction type: Suzuki-Miyaura Coupling

form

powder or crystals

form

solid

form

solid

form

solid

functional group

phosphine

functional group

phosphine

functional group

phosphine

functional group

phosphine

mp

263 °C (Decomp)

mp

193-194 °C (decomposition)

mp

130-140 °C

mp

146-151 °C (decomposition)


Storage Class

11 - Combustible Solids

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable



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