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D62004

cis-1,2-Dichloroethylene

97%

Synonym(s):

cis-1,2-DCE, cis-Acetylene dichloride

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Size/SKUAvailabilityPrice
1 g
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$43.80
10 g
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$237.00
50 g
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$678.00
$508.50

About This Item

Linear Formula:
ClCH=CHCl
CAS Number:
Molecular Weight:
96.94
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
205-859-7
Beilstein/REAXYS Number:
1071208
MDL number:
Assay:
97%
Form:
liquid

$43.80


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Quality Segment

assay

97%

form

liquid

refractive index

n20/D 1.449 (lit.)

bp

60 °C (lit.)

mp

−80 °C (lit.)

density

1.284 g/mL at 25 °C (lit.)

SMILES string

Cl\C=C/Cl

InChI

1S/C2H2Cl2/c3-1-2-4/h1-2H/b2-1-

InChI key

KFUSEUYYWQURPO-UPHRSURJSA-N

Application

cis-1,2-Dichloroethylene (cis-1,2-DCE) is generally used in the preparation of various enediynes for Bergman cyclization. Applications include the synthesis of:
  • 2-(6-substituted 3(Z)-hexen-1,5-diynyl)anilines to prepare corresponding substituted carbazoles.
  • (Z)-1-aryl-3-henen-1,5-diynes to obtain the corresponding aryl substituted benzotriazoles.


It is used as a linker to synthesize boron-dipyrromethene (BODIPY)-based photosensitizer for photodynamic therapy (PDT). cis-1,2-DCE can also be used as a precursor to synthesize intermediates of sporolide B.

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This Item
D6220937741448597
description

97%

description

98%

description

97%

description

analytical standard

assay

97%

assay

98%

assay

97%

assay

-

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

refractive index

n20/D 1.449 (lit.)

refractive index

n20/D 1.446 (lit.)

refractive index

n20/D 1.4675 (lit.)

refractive index

n20/D 1.449 (lit.)

density

1.284 g/mL at 25 °C (lit.)

density

1.257 g/mL at 25 °C (lit.)

density

1.225 g/mL at 25 °C (lit.)

density

1.284 g/mL at 25 °C (lit.)

bp

60 °C (lit.)

bp

48 °C (lit.)

bp

104 °C (lit.)

bp

60 °C (lit.)

mp

−80 °C (lit.)

mp

−50 °C (lit.)

mp

-

mp

−80 °C (lit.)


pictograms

FlameExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Flam. Liq. 2 - Skin Irrit. 2

Storage Class

3 - Flammable liquids

flash_point_f

42.8 °F - closed cup

flash_point_c

6.0 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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