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15230

[Bis(trifluoroacetoxy)iodo]benzene

purum, ≥95.0% (AT)

Synonym(s):

BTI, Iodobenzene I,I-bis(trifluoroacetate), PIFA

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Size/SKUAvailabilityPrice
10 g

Available to ship TODAY

$102.00
50 g

Available to ship TODAY

$219.00

About This Item

Linear Formula:
(CF3CO2)2IC6H5
CAS Number:
Molecular Weight:
430.04
UNSPSC Code:
12352002
NACRES:
NA.22
PubChem Substance ID:
EC Number:
220-308-0
Beilstein/REAXYS Number:
764767
MDL number:
Assay:
≥95.0% (AT)
Form:
solid

$102.00


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grade

purum

Quality Segment

assay

≥95.0% (AT)

form

solid

reaction suitability

reagent type: oxidant

mp

121-125 °C (lit.), 122-125 °C

functional group

fluoro, iodo

SMILES string

FC(F)(F)C(=O)O[I](OC(=O)C(F)(F)F)c1ccccc1

InChI

1S/C10H5F6IO4/c11-9(12,13)7(18)20-17(6-4-2-1-3-5-6)21-8(19)10(14,15)16/h1-5H

InChI key

PEZNEXFPRSOYPL-UHFFFAOYSA-N

Application

Reactant or reagent for:
  • Pummerer-like reactions
  • Chemoselective deprotection of dimethoxybenzyl ethers
  • Mediating oxidative cycloisomerization
  • Tosyloxylation of anilides

Other Notes

Reagent for dehydrogenation and oxidation reactions, review; New reagent for the direct conversions of amides to amines (Hofmann-type rearrangement) and key substance for carboxyterminal peptide sequencing; Smooth dethioacetalization to the carbonyls

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This Item
232130394111927120
description

purum, ≥95.0% (AT)

description

97%

description

ULTROL® Grade, >98% (titration), non-zwitterionic buffer useful in pH range 6.3-9.5

description

≥95%

assay

≥95.0% (AT)

assay

97%

assay

>98% (titration)

assay

≥95%

reaction suitability

reagent type: oxidant

reaction suitability

reagent type: oxidant

reaction suitability

-

reaction suitability

reagent type: ligand
reaction type: Ullmann Reaction

Quality Level

200

Quality Level

200

Quality Level

100

Quality Level

100

form

solid

form

solid

form

solid

form

powder

mp

122-125 °C, 121-125 °C (lit.)

mp

121-125 °C (lit.)

mp

-

mp

-

functional group

iodo, fluoro

functional group

fluoro, iodo

functional group

-

functional group

-


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Pictograms

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Signal Word

Warning

Hazard Codes

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

PPE (personal protective equipment)

dust mask type N95 (US), Eyeshields, Gloves



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