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156256

Sodium methoxide solution

25 wt. % in methanol, solution

Synonym(s):

Sodium methylate

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Size/SKUAvailabilityPrice
25 mL
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$55.80
1 L
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$78.10
2.5 L
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$152.00
18 L
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$565.00

About This Item

Linear Formula:
CH3ONa
CAS Number:
Molecular Weight:
54.02
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Beilstein/REAXYS Number:
3592982
Form:
liquid

$55.80


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Product Name

Sodium methoxide solution, 25 wt. % in methanol

vapor density

1.1 (vs air)

Quality Segment

vapor pressure

50 mmHg ( 20 °C), 96 mmHg ( 25 °C)

form

liquid

autoignition temp.

878 °F

concentration

25 wt. % in methanol

refractive index

n20/D 1.37

density

0.945 g/mL at 25 °C

SMILES string

[Na+].C[O-]

InChI

1S/CH3O.Na/c1-2;/h1H3;/q-1;+1

InChI key

WQDUMFSSJAZKTM-UHFFFAOYSA-N

General description

The product is 25wt.% solution of sodium methoxide in methanol. Its reaction with unactivated aryl bromides in the presence of copper catalyst under various reaction conditions has been studied. It reacts with aryl halides in the presence of a palladium catalyst in DMF (Dimethylformamide) to afford arenes.

Application

Sodium methoxide solution has been used in the synthesis of NO-containing nanoparticles (SNO-NP).
A novel high-spin hexanuclear Mn(III) cluster, [NaMn6(OMe)12(dbm)6]+, was synthesized via MnCl2 oxidation with simultaneous NaOMe promoted aggregation. This cluster has an unprecedented cyclic structure and 24 unpaired electrons in its ground state.

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This Item
40306792446164992
description

25 wt. % in methanol

description

ACS reagent, 0.5 M CH3ONa in methanol (0.5N)

description

derivatization grade (GC derivatization), 0.5 M

description

reagent grade, 95%, powder

form

liquid

form

liquid

form

liquid

form

powder

Quality Level

200

Quality Level

200

Quality Level

100

Quality Level

200

vapor pressure

96 mmHg ( 25 °C), 50 mmHg ( 20 °C)

vapor pressure

-

vapor pressure

-

vapor pressure

50 mmHg ( 20 °C)

density

0.945 g/mL at 25 °C

density

0.809 g/mL at 25 °C

density

0.805-0.817 g/mL at 20 °C

density

-

refractive index

n20/D 1.37

refractive index

-

refractive index

-

refractive index

-

vapor density

1.1 (vs air)

vapor density

-

vapor density

-

vapor density

1.1 (vs air)


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Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - Skin Corr. 1A - STOT SE 1

Target Organs

Eyes,Central nervous system

supp_hazards

Storage Class

3 - Flammable liquids

Flash Point (°F)

60.0 °F - closed cup - Solvent

Flash Point (°C)

15.55 °C - closed cup - Solvent



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Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. HI, does the Sodium methoxide solution come in a Sure-seal bottle?

    1 answer
    1. Product 156256, Sodium methoxide solution is not packaged in a Sure/Seal™ bottle. The 156256-25mL, 156256-1L, and 156256-2.5L SKUs are packaged in amber glass bottles with PP caps and HDPE/PTFE liners. The 156256-18L is packaged in a carbon steel drum.

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