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228036

OXONE®, monopersulfate compound

Synonym(s):

Potassium peroxymonosulfate

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5 g

Available to ship TODAY

$53.20
100 g

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$64.80
1 kg

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$88.70
5 kg

Available to ship TODAYfromMILWAUKEE

$397.00
25 kg

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$746.00

About This Item

Linear Formula:
KHSO5 · 0.5KHSO4 · 0.5K2SO4
CAS Number:
Molecular Weight:
307.38
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352300
MDL number:
Form:
powder

$53.20


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vapor pressure

<0.0000017 hPa

Quality Segment

form

powder

reaction suitability

reagent type: oxidant

concentration

>4.0% (active oxygen basis (by Na2S2O3, titration))

pH

2.1 (77 °C, 30 g/L)

SMILES string

[K+].[K+].[K+].[K+].[K+].OS([O-])(=O)=O.[O-]S([O-])(=O)=O.O[S+]([O-])([O-])(=O)=O.O[S+]([O-])([O-])(=O)=O

InChI

1S/5K.2H2O5S.2H2O4S/c;;;;;2*1-5-6(2,3)4;2*1-5(2,3)4/h;;;;;2*1H,(H,2,3,4);2*(H2,1,2,3,4)/q5*+1;;;;/p-5

InChI key

HJKYXKSLRZKNSI-UHFFFAOYSA-I

General description

OXONE®, monopersulfate compound is a potassium triple salt mainly used as a stable, easy to handle and nontoxic oxidant.

Application

OXONE®, monopersulfate compound may be used as an alternative to transition-metal oxidants for the conversion of aldehydes to carboxylic acids or esters.
Oxidant used for halogenation of α,β-unsaturated carbonyl compounds and catalytic generation of hypervalent iodine reagents for alcohol oxidation.
A rapid, efficient synthesis of oxaziridines from imines using buffered OXONE has been reported. Also used to study fading of an artist′s colorants.

Legal Information

OXONE is a registered trademark of E. I. du Pont de Nemours and Company

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description

-

description

free-flowing, Redi-Dri

description

ReagentPlus®, ~99%

description

anhydrous, free-flowing, Redi-Dri, ACS reagent, ≥98%

form

powder

form

powder

form

powder or crystals

form

powder

Quality Level

200

Quality Level

-

Quality Level

200

Quality Level

200

pH

2.1 (77 °C, 30 g/L)

pH

2-3 (10 g/L in aqueous solution, pH <6.0)

pH

6-9 (25 °C, 329 g/L)

pH

8.5-9.6 (25 °C, 5% in solution)

vapor pressure

<0.0000017 hPa

vapor pressure

-

vapor pressure

-

vapor pressure

-

concentration

>4.0% (active oxygen basis (by Na2S2O3, titration))

concentration

>4.0% (active oxygen, titration by Na2S2O3 )

concentration

-

concentration

-

reaction suitability

reagent type: oxidant

reaction suitability

-

reaction suitability

-

reaction suitability

-


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Signal Word

Danger

Hazard Codes

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B

PPE (personal protective equipment)

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Storage Class

8B - Non-combustible corrosive hazardous materials

Flash Point (°F)

does not flash

Flash Point (°C)

does not flash



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Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. do you need explosive rated fans to operate around Oxone?

    1 answer
    1. The Safety Data Sheet classifies this material as non-explosive therefore there is no need for explosive rated fans in order to operate around OXONE®, monopersulfate compound Product 228036-100G.

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