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242586

Diphenylamine

ACS reagent grade, ≥99%

Synonym(s):

DPA

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Pack SizeSKUAvailabilityPrice
5 g
Please contact Customer Service for Availability
HUF 20,400.00
100 g
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HUF 39,300.00
500 g
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HUF 83,500.00

About This Item

Linear Formula:
(C6H5)2NH
CAS Number:
Molecular Weight:
169.22
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
204-539-4
MDL number:
Beilstein/REAXYS Number:
508755
Assay:
≥99%

HUF 20,400.00


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Product Name

Diphenylamine, ACS reagent, ≥99%

grade

ACS reagent

Quality Level

vapor density

5.82 (vs air)

vapor pressure

1 mmHg ( 108 °C)

assay

≥99%

autoignition temp.

1175 °F

ign. residue

≤0.03%

bp

302 °C (lit.)

mp

50-53 °C (lit.)

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This Item
33149112763CRM69121
assay

≥99%

assay

≥98% (GC)

assay

99%

assay

-

Quality Level

200

Quality Level

200

Quality Level

100

Quality Level

300

solubility

alcohol: passes test

solubility

-

solubility

water: insoluble

solubility

-

bp

302 °C (lit.)

bp

302 °C (lit.)

bp

302 °C (lit.)

bp

302 °C (lit.)

mp

50-53 °C (lit.)

mp

50-53 °C (lit.), 52.5-54.0 °C

mp

50-53 °C (lit.)

mp

50-53 °C (lit.)

anion traces

nitrate (NO3-): passes test

anion traces

nitrate (NO3-): in accordance

anion traces

-

anion traces

-

Application

Diphenylamine can undergo palladium-catalyzed intramolecular cyclization to form carbazole. It may also be used as a starting material in the synthesis of triphenylamine.
Diphenylamine may be used in the preparation of diphenylamine reagent, which is employed for the quantitative estimation of nucleic acid (DNA) from various biological sources by colorimetric method.[1]

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2

target_organs

Kidney,Liver,spleen

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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Palladium-promoted cyclization of diphenyl ether, diphenylamine, and related compounds.
Akermark B, et al.
The Journal of Organic Chemistry, 40(9), 1365-1367 (1975)
Triphenylamine
Hager FD
Organic Syntheses, 8(116), 116-116 (1928)
An improved diphenylamine method for the estimation of deoxyribonucleic acid.
Giles KW and Myers A.
Nature, 206(4979), 93-93 (1965)
Soluble and methane sulfonic acid doped poly (diphenylamine)-synthesis and characterization.
Wen T-C, et al.
Materials Letters, 57(2), 280-290 (2002)
Sarah G Pati et al.
Environmental science & technology, 46(21), 11844-11853 (2012-09-29)
Dioxygenation of aromatic rings is frequently the initial step of biodegradation of organic subsurface pollutants. This process can be tracked by compound-specific isotope analysis to assess the extent of contaminant transformation, but the corresponding isotope effects, especially for dioxygenation of

Global Trade Item Number

SKUGTIN
PH017019-1G04054839945328
242586-100G04061835365470
242586-500G04061825589497
242586-5G04061835365487

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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