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40390

Dimethylglyoxime

ACS reagent grade, ≥99.0% (TLC), solid, suitable for UV/Vis spectroscopy, for the detection of Ni, puriss. p.a.

Synonym(s):

2,3-Butanedione dioxime, Diacetyldioxime

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Size/SKUAvailabilityPrice
25 g
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$62.40
100 g
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$74.80
500 g
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$165.00

About This Item

Linear Formula:
CH3C(=NOH)C(=NOH)CH3
CAS Number:
Molecular Weight:
116.12
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
202-420-1
MDL number:
Beilstein/REAXYS Number:
506731
Assay:
≥99.0% (TLC)
Form:
solid

$62.40


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Product Name

Dimethylglyoxime, puriss. p.a., ACS reagent, for the detection of Ni, ≥99.0% (TLC)

Quality Segment

grade

ACS reagent, puriss. p.a.

assay

≥99.0% (TLC)

form

solid

quality

for the detection of Ni

technique(s)

UV/Vis spectroscopy: suitable

impurities

≤0.02% insoluble matter in ethanol

ign. residue

≤0.05% (as SO4)

mp

240-241 °C (lit.)

solubility

water: soluble 0.1 g/10 mL, clear, colorless

cation traces

Ca: ≤10 mg/kg, Cd: ≤5 mg/kg, Co: ≤5 mg/kg, Cr: ≤5 mg/kg, Cu: ≤5 mg/kg, Fe: ≤5 mg/kg, K: ≤50 mg/kg, Mg: ≤5 mg/kg, Mn: ≤5 mg/kg, Na: ≤50 mg/kg, Ni: ≤5 mg/kg, Pb: ≤5 mg/kg, Zn: ≤5 mg/kg

functional group

amine, oxime

SMILES string

CC(=N/O)\C(C)=N\O

InChI

1S/C4H8N2O2/c1-3(5-7)4(2)6-8/h7-8H,1-2H3/b5-3+,6-4+

InChI key

JGUQDUKBUKFFRO-GGWOSOGESA-N

General description

Dimethylglyoxime (DMG) is a complexing ligand. Dimethylglyoxime forms a number of mixed ligand complexes with N-acetylglycine with metals such as VO(IV), Ni(II), Zn(II), Pd(II), Cd(II) and Pb(II). It is a useful reagent for the spectrophotometric determination of Co(II), Fe(II), Ni(II), Pd(II) and Re(VII).

Application

Dimethylglyoxime (DMG) was used as complexing agent for cobalt(II) and nickel(II) metals for the analysis of brine for trace metals by adsorptive stripping voltammetry. DMG was used in a study to develop a new DMG containing modified sol-gel carbon composite electrode for voltammetric sensing of heavy metals.

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This Item
0385843820237655
description

puriss. p.a., ACS reagent, for the detection of Ni, ≥99.0% (TLC)

description

≥97.0% (TLC)

description

ACS reagent, for spectrophotometric det. of Cd, Cu, Hg, Pb, Zn, ≥98.0% (TLC)

description

98%

assay

≥99.0% (TLC)

assay

≥97.0% (TLC)

assay

≥98.0% (TLC)

assay

98%

Quality Level

200

Quality Level

100

Quality Level

200

Quality Level

100

solubility

water: soluble 0.1 g/10 mL, clear, colorless

solubility

-

solubility

-

solubility

-

form

solid

form

powder

form

powder

form

-

mp

240-241 °C (lit.)

mp

240-241 °C (lit.)

mp

168 °C (dec.) (lit.)

mp

88-90 °C (lit.)

technique(s)

UV/Vis spectroscopy: suitable

technique(s)

-

technique(s)

UV/Vis spectroscopy: suitable

technique(s)

-


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Pictograms

Flame

Signal Word

Warning

Hazard Codes

Hazard Classifications

Flam. Sol. 2

Storage Class

4.1B - Flammable solid hazardous materials

WGK

WGK 3

PPE (personal protective equipment)

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges



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