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539996

Acetic anhydride

99.5%

Synonym(s):

Acetanhydride, Acetic acid anhydride, Acetyl acetate, Acetyl anhydride, Ethanoic anhydride

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25 g

Available to ship TODAY

$46.40
1 kg

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$112.00
4 kg

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$232.00
18 kg

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$636.00

About This Item

Linear Formula:
(CH3CO)2O
CAS Number:
Molecular Weight:
102.09
UNSPSC Code:
12352100
NACRES:
NA.21
PubChem Substance ID:
EC Number:
203-564-8
Beilstein/REAXYS Number:
385737
MDL number:
Assay:
99.5%

$46.40


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vapor density

3.5 (vs air)

Quality Segment

vapor pressure

10 mmHg ( 36 °C), 4 mmHg ( 20 °C)

assay

99.5%

autoignition temp.

629 °F

expl. lim.

10.3 %

refractive index

n20/D 1.390 (lit.)

bp

138-140 °C (lit.)

mp

−73 °C (lit.)

solubility

water: slightly soluble

density

1.08 g/mL (lit.)

functional group

anhydride, ester

SMILES string

CC(=O)OC(C)=O

InChI

1S/C4H6O3/c1-3(5)7-4(2)6/h1-2H3

InChI key

WFDIJRYMOXRFFG-UHFFFAOYSA-N

General description

Acetic anhydride is a carboxylic acid anhydride commonly used for the acetylation of amines and alcohols. It undergoes exothermic reaction on addition of water to form acetic acid. The photodecomposition of acetic anhydride has been studied over the temperature range from 60-160°C. The impact of treating pine wood with acetic anhydride has been investigated to evaluate the toughness of pine wood.

Application

Acetic anhydride has been used in the preparation of 6-dimethylamino-2,3-naphthalenedicarboxylic anhydride. It has also been used to generate acetate ions during high resolution chemical ionization mass spectrometry (CI-ToFMS) analysis.

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This Item
AX008069127533214
description

99.5%

description

Meets ACS Specifications, Meets Reagent Specifications for testing USP/NF monographs GR ACS

description

Arxada quality, ≥99.5% (GC)

description

puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., ≥99% (GC)

assay

99.5%

assay

≥99.0% (GC)

assay

≥99.5% (GC)

assay

≥99% (GC)

solubility

water: slightly soluble

solubility

-

solubility

H2O: slightly soluble

solubility

-

Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

200

refractive index

n20/D 1.390 (lit.)

refractive index

-

refractive index

n20/D 1.390 (lit.)

refractive index

n20/D 1.390 (lit.)

mp

−73 °C (lit.)

mp

-73 °C

mp

−73 °C (lit.)

mp

−73 °C (lit.)

bp

138-140 °C (lit.)

bp

-

bp

138-140 °C (lit.)

bp

138-140 °C (lit.)


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Signal Word

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B

Storage Class

3 - Flammable liquids

Flash Point (°F)

120.2 °F - closed cup

Flash Point (°C)

49 °C - closed cup

PPE (personal protective equipment)

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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