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902217

Ir[dFFppy]2-(4,4′-dCF3bpy)PF6

≥95%, powder or crystals

Sustainability features

Synonym(s):

Ir photocatalyst, Photocatalyst

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Size/SKUAvailabilityPrice
100 mg
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$149.00
500 mg
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$710.00

About This Item

Empirical Formula (Hill Notation):
C34H16F18IrN4P
CAS Number:
2030437-92-2
Molecular Weight:
1045.68
MDL number:
MFCD27952560
UNSPSC Code:
12161600
NACRES:
NA.22

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Product Name

Ir[dFFppy]2-(4,4′-dCF3bpy)PF6, ≥95%

assay

≥95%

form

powder or crystals

reaction suitability

core: iridium, reagent type: catalyst
reaction type: Photocatalysis

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Sustainability features

mp

>300 °C

photocatalyst activation

450 nm

greener alternative category

SMILES string

[Ir+]741([NH]8=C(c9c7cc(cc9F)F)C=CC(=C8)F)([NH]5=CC(=CC=C5c6c4cc(cc6F)F)F)[NH]2=CC=C(C=C2C3=CC(=CC=[NH]31)C(F)(F)F)C(F)(F)F.F[P-](F)(F)(F)(F)F

InChI key

UCNIZYCFAFBGQB-UHFFFAOYSA-N

General description

Sustainability Features: Aligned with Green Chemistry principle, ′Catalysis,′ this product is an advanced Hoveyda-Grubbs type catalyst for specialized metathesis applications. It provides superior performance in sterically demanding ring-closing metathesis reactions. Click here for more information.

Application

Under a dual catalytic copper/photoredox manifold, the Mes-Umemoto reagent has been demonstrated to be an excellent photocatalyst for the trifluoromethylation of alkyl halides and aryl halides to yield alkyl-CF3 and aryl-CF3 in high yields. In both cases, these reactions exhibit wide substrate scope with good functional group tolerance. More specifically, a variety of 5-membered and 6-membered heteroaryl halides can be readily converted to the corresponding trifluoromethylheteroarenes under mild conditions. For trifluoromethylation reactions, use with dMesSCF3 (901466) and supersilanol (902489).

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

A radical approach to the copper oxidative addition problem:Trifluoromethylation of bromoarenes

Catalytic alkylation of remote C-H bonds enabled by proton-coupled electron transfer

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Ir[dFFppy]2-(4,4′-dCF3bpy)PF6 ≥95%

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Ir[dFMeppy]2-(4,4′-dCF3bpy)PF6

[Ir(dFOMeppy)2-(5,5′-dCF3bpy)]PF6 ≥95%

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911607

[Ir(dFOMeppy)2-(5,5′-dCF3bpy)]PF6

[Ir(dFCF3ppy)2-(5,5’-dCF3bpy)]PF6 ≥95%

Sigma-Aldrich

908568

[Ir(dFCF3ppy)2-(5,5′-dCF3bpy)]PF6

description

≥95%

description

≥95%

description

≥95%

description

≥95%

assay

≥95%

assay

≥95%

assay

≥95%

assay

≥95%

reaction suitability

core: iridium, reagent type: catalyst
reaction type: Photocatalysis

reaction suitability

core: iridium, reagent type: catalyst, reaction type: Photocatalysis

reaction suitability

reagent type: catalyst, reaction type: Photocatalysis

reaction suitability

reaction type: Photocatalysis, reagent type: catalyst

form

powder or crystals

form

powder

form

powder or crystals

form

powder or crystals

mp

>300 °C

mp

>300 °C

mp

>300 °C

mp

>300 °C

photocatalyst activation

450 nm

photocatalyst activation

-

photocatalyst activation

465 nm

photocatalyst activation

460 nm

Storage Class

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

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