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902225

Ir[dFMeppy]2-(4,4′-dCF3bpy)PF6

≥95%, powder

Synonym(s):

Photocatalyst

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Size/SKUAvailabilityPrice
100 mg

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$238.00
$249.00

About This Item

Empirical Formula (Hill Notation):
C36H22F16IrN4P
CAS Number:
2229858-27-7
Molecular Weight:
1037.75
MDL number:
MFCD32857514
UNSPSC Code:
12161602
NACRES:
NA.22

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Product Name

Ir[dFMeppy]2-(4,4′-dCF3bpy)PF6, ≥95%

assay

≥95%

form

powder

reaction suitability

core: iridium, reaction type: Photocatalysis, reagent type: catalyst

mp

>300 °C

SMILES string

FC1=CC(F)=C2C3=CC=C(C=[N]3[Ir+3]45([C-]2=C1)([C-]6=CC(F)=CC(F)=C6C7=CC=C(C=[N]74)C)[N]8=CC=C(C=C8C=9C=C(C=C[N]95)C(F)(F)F)C(F)(F)F)C.[F-][P+5]([F-])([F-])([F-])([F-])[F-]

InChI

InChI=1S/C12H6F6N2.2C12H8F2N.F6P.Ir/c13-11(14,15)7-1-3-19-9(5-7)10-6-8(2-4-20-10)12(16,17)18;2*1-8-2-5-12(15-7-8)10-4-3-9(13)6-11(10)14;1-7(2,3,4,5)6;/h1-6H;2*2-3,5-7H,1H3;;/q;3*-1;+3

InChI key

RYKRFKQFYGHADE-UHFFFAOYSA-N

Application

Under a dual catalytic copper/photoredox manifold, the Mes-Umemoto reagent has been demonstrated to be an excellent photocatalyst for the trifluoromethylation of alkyl halides and aryl halides to yield alkyl-CF3 and aryl-CF3 in high yields. In both cases, these reactions exhibit wide substrate scope with good functional group tolerance. More specifically, a variety of 5-membered and 6-membered heteroaryl halides can be readily converted to the corresponding trifluoromethylheteroarenes under mild conditions. For trifluoromethylation reactions, use with dMesSCF3 (901466) and supersilanol (902489).

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

A radical approach to the copper oxidative addition problem:Trifluoromethylation of bromoarenes

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Ir[dFMeppy]2-(4,4′-dCF3bpy)PF6 ≥95%

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[Ir(dFOMeppy)2-(5,5′-dCF3bpy)]PF6 ≥95%

Sigma-Aldrich

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[Ir(dFCF3ppy)2-(5,5’-dCF3bpy)]PF6 ≥95%

Sigma-Aldrich

908568

[Ir(dFCF3ppy)2-(5,5′-dCF3bpy)]PF6

description

≥95%

description

≥95%

description

≥95%

description

≥95%

assay

≥95%

assay

≥95%

assay

≥95%

assay

≥95%

reaction suitability

reagent type: catalyst, core: iridium, reaction type: Photocatalysis

reaction suitability

reagent type: catalyst
reaction type: Photocatalysis, core: iridium

reaction suitability

reaction type: Photocatalysis, reagent type: catalyst

reaction suitability

reaction type: Photocatalysis, reagent type: catalyst

form

powder

form

powder or crystals

form

powder or crystals

form

powder or crystals

mp

>300 °C

mp

>300 °C

mp

>300 °C

mp

>300 °C

Storage Class

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

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