If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
91741
Trimethylsilyl trifluoromethanesulfonate
purum, ≥98.0% (T)
Synonym(s):
TMS triflate, TMSOTf, Trifluoromethanesulfonic acid trimethylsilylester
Select a Size
| Size/SKU | Availability | Price |
|---|---|---|
10 mL | Available to ship TODAYfromMILWAUKEE | $65.20 |
50 mL | Available to ship TODAYfromMILWAUKEE | $242.00 $181.50 |
250 mL | Available to ship TODAYfromMILWAUKEE | $726.00 |
About This Item
$65.20
Available to ship TODAYDetails
grade
purum
Quality Segment
assay
≥98.0% (T)
form
liquid
reaction suitability
reactivity: alcohol reactive, reagent type: protection reagent
refractive index
n20/D 1.36 (lit.)
bp
77 °C/80 mmHg (lit.)
density
1.228 g/mL at 25 °C (lit.)
functional group
fluoro, triflate
SMILES string
C[Si](C)(C)OS(=O)(=O)C(F)(F)F
InChI
1S/C4H9F3O3SSi/c1-12(2,3)10-11(8,9)4(5,6)7/h1-3H3
InChI key
FTVLMFQEYACZNP-UHFFFAOYSA-N
Application
- Allylation of acetals to form homoallyl ethers.
- Synthesis of 1,2-trans-glycosides.
- Conversion of alcohols to esters.
- Aminomethylation of silyl enol ethers with aminomethyl alkyl ethers.
- Glycosidation of (+)-4-demethoxyanthracyclinones.
Other Notes
1 of 1
This Item | |||
|---|---|---|---|
| description purum, ≥98.0% (T) | description 97% | description 98% | description ≥99.95% trace metals basis |
| assay ≥98.0% (T) | assay 97% | assay 98% | assay ≥99.95% trace metals basis |
| Quality Level 200 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
| reaction suitability reagent type: protection reagent, reactivity: alcohol reactive | reaction suitability - | reaction suitability - | reaction suitability reagent type: catalyst, core: silver |
| refractive index n20/D 1.36 (lit.) | refractive index - | refractive index - | refractive index - |
| bp 77 °C/80 mmHg (lit.) | bp - | bp - | bp - |
| density 1.228 g/mL at 25 °C (lit.) | density - | density - | density - |
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signalword
Danger
hcodes
Hazard Classifications
Flam. Liq. 3 - Skin Corr. 1B
supp_hazards
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
77.0 °F - closed cup
flash_point_c
25 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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How can I determine the shelf life / expiration / retest date of this product?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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Does this product come in a glass bottle? I would prefer not to buy an ampule.
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This product is packaged in amber glass bottles with ETFE screw caps.
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