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918342

CX231

Umicore, powder

Synonym(s):

Chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene](1-tert-butyl-1H-inden-1-yl)palladium(II), [(IPr)Pd(1-tBu-Ind)Cl]

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Size/SKUAvailabilityPrice
1 g
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$340.00

About This Item

Empirical Formula (Hill Notation):
C40H51ClN2Pd
CAS Number:
Molecular Weight:
701.72
MDL number:
UNSPSC Code:
12352101
NACRES:
NA.22

$340.00


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Product Name

CX231, Umicore

Quality Segment

form

powder

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

mp

>300 °C

SMILES string

[Pd](Cl)(C3N(C=CN3c5c(cccc5C(C)C)C(C)C)c4c(cccc4C(C)C)C(C)C)C.[C@@H]1(CCc2c1cccc2)C(C)(C)C

InChI

1S/C27H37N2.C13H18.CH3.ClH.Pd/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;1-13(2,3)12-9-8-10-6-4-5-7-11(10)12;;;/h9-21H,1-8H3;4-7,12H,8-9H2,1-3H3;1H3;1H;/q;;;;+1/p-1/t;12-;;;/m.0.../s1

InChI key

SQHBIBNOWKZNLF-ZDJNGQJDSA-M

Application

Umicore CX231 is a homogeneous catalyst useful for cross-coupling reactions with arenes, Buchwald-Hartwig aminaton reactions, and Suzuki-Miyaura cross-couplings.

Preparation Note

Do not store above 25°C (77°F). Store in a tightly closed original container under dry inert gas, protected from direct sunlight in a dry, cool and well-ventilated area.

Legal Information

Product of Umicore

This product, its manufacturing or use, is the subject of one or more issued or pending U.S. Patents (and foreign equivalents) owned or controlled by Umicore PMC. The purchase of this product from Umicore PMC through Sigma-Aldrich, its affiliates or their authorized distributors conveys to the buyer a limited, one-time, non-exclusive, non-transferable, non-assignable license. Buyer′s use of this product may infringe patents owned or controlled by third parties. It is the sole responsibility of buyer to ensure that its use of the product does not infringe the patent rights of third parties or exceed the scope of the license granted herein.

Additional information available at www.pmc.umicore.com

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This Item
918598931209915238
description

Umicore

description

Umicore

description

Umicore

description

Umicore

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

reaction suitability

-

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

form

powder

form

powder

form

powder

form

powder

mp

>300 °C

mp

>300 °C

mp

-

mp

187-189 °C


Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



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