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T35955

p-Toluenesulfonyl chloride

reagent grade, ≥98%

Synonym(s):

Tosyl chloride

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Size/SKUAvailabilityPrice
1 kg
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$122.00
3 kg
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$245.00

About This Item

Linear Formula:
CH3C6H4SO2Cl
CAS Number:
Molecular Weight:
190.65
UNSPSC Code:
12352100
NACRES:
NA.21
PubChem Substance ID:
EC Number:
202-684-8
Beilstein/REAXYS Number:
607898
MDL number:
Assay:
≥98%

$122.00


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grade

reagent grade

Quality Segment

vapor pressure

1 mmHg ( 88 °C)

assay

≥98%

reaction suitability

reactivity: alcohol reactive, reactivity: amine reactive, reagent type: protection reagent

bp

134 °C/10 mmHg (lit.)

mp

65-69 °C (lit.)

SMILES string

Cc1ccc(cc1)S(Cl)(=O)=O

InChI

1S/C7H7ClO2S/c1-6-2-4-7(5-3-6)11(8,9)10/h2-5H,1H3

InChI key

YYROPELSRYBVMQ-UHFFFAOYSA-N

Application

p-toluenesulfonyl chloride may be used along with N-methylimidazole for the esterification or thioesterification of carboxylic acids and alcohols or thiols. It may also be used as a chlorine source for α-chlorination of ketones in the presence of lithium diisopropylamide.

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This Item
240877402885T35920
description

reagent grade, ≥98%

description

ReagentPlus®, ≥99%

description

ACS reagent, ≥98.5%

description

ReagentPlus®, ≥98%

assay

≥98%

assay

≥99%

assay

≥98.5%

assay

≥98%

Quality Level

200

Quality Level

200

Quality Level

300

Quality Level

200

reaction suitability

reagent type: protection reagent, reactivity: amine reactive, reactivity: alcohol reactive

reaction suitability

reagent type: protection reagent, reactivity: amine reactive, reactivity: alcohol reactive

reaction suitability

-

reaction suitability

-

mp

65-69 °C (lit.)

mp

65-69 °C (lit.)

mp

103-106 °C (lit.)

mp

103-106 °C (lit.), 103-106 °C ((lit.))

bp

134 °C/10 mmHg (lit.)

bp

134 °C/10 mmHg (lit.)

bp

-

bp

-

vapor pressure

1 mmHg ( 88 °C)

vapor pressure

1 mmHg ( 88 °C)

vapor pressure

-

vapor pressure

-


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Pictograms

CorrosionExclamation mark

Signal Word

Danger

Hazard Classifications

Eye Dam. 1 - Met. Corr. 1 - Skin Irrit. 2 - Skin Sens. 1

Flash Point (°F)

262.4 °F - closed cup

Flash Point (°C)

128 °C - closed cup

PPE (personal protective equipment)

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Storage Class

11 - Combustible Solids



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

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