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20989

Cesium fluoride

BioUltra, ≥99.0% (F)

Synonym(s):

NSC 84270

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About This Item

Empirical Formula (Hill Notation):
CsF
CAS Number:
Molecular Weight:
151.90
NACRES:
NA.25
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
236-487-3
MDL number:
Assay:
≥99.0% (F)
Grade:
reagent grade
Solubility:
H2O: 3 M at 20 °C, clear, colorless
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grade

reagent grade

Quality Segment

product line

BioUltra

assay

≥99.0% (F)

impurities

insoluble matter, passes filter test, ≤0.005% total nitrogen (N)

loss

≤0.5% loss on drying, 110 °C

pH

6.5-7.5 (25 °C, 3 M in H2O)

mp

682 °C (lit.)

solubility

H2O: 3 M at 20 °C, clear, colorless

density

4.115 g/mL at 25 °C (lit.)

anion traces

chloride (Cl-): ≤500 mg/kg, sulfate (SO42-): ≤50 mg/kg

cation traces

Al: ≤10 mg/kg, As: ≤0.5 mg/kg, Ba: ≤10 mg/kg, Bi: ≤5 mg/kg, Ca: ≤10 mg/kg, Cd: ≤5 mg/kg, Co: ≤5 mg/kg, Cr: ≤5 mg/kg, Cu: ≤5 mg/kg, Fe: ≤30 mg/kg, K: ≤100 mg/kg, Li: ≤5 mg/kg, Mg: ≤5 mg/kg, Mn: ≤5 mg/kg, Mo: ≤5 mg/kg, Na: ≤50 mg/kg, Ni: ≤5 mg/kg, Pb: ≤5 mg/kg, Sr: ≤5 mg/kg, Zn: ≤5 mg/kg

λ

3 M in H2O

UV absorption

λ: 260 nm Amax: 0.05, λ: 280 nm Amax: 0.05

SMILES string

[F-].[Cs+]

InChI

1S/Cs.FH/h;1H/q+1;/p-1

InChI key

XJHCXCQVJFPJIK-UHFFFAOYSA-M

Application

Reactant for:
  • Preparation of building blocks for synthesis of fluoroallylic compounds
  • Synthesis of alcohols via hydrolysis of alkyl silyl ethers at neutral pH in buffered mixed organic-aqueous solutions
  • Nucleophilic fluorination of alkynyliodonium salts to form fluorovinylic compounds
  • Nucleophilic aromatic substitution (SNAr) reactions
Used in the successful synthesis of a single-crystal Dion-Jacobson phase, CsLaTa2O7, that has applications in photocatalysis and superconductivity.

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This Item
25571825571820990
solubility

H2O: 3 M at 20 °C, clear, colorless

solubility

methanol: slightly soluble(lit.), pyridine: insoluble(lit.)

solubility

methanol: slightly soluble(lit.), pyridine: insoluble(lit.)

solubility

-

assay

≥99.0% (F)

assay

99.99% trace metals basis

assay

99.99% trace metals basis

assay

≥98.0%

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

grade

reagent grade

grade

-

grade

-

grade

-

impurities

insoluble matter, passes filter test, ≤0.005% total nitrogen (N)

impurities

≤150.0 ppm Trace Metal Analysis

impurities

≤150.0 ppm Trace Metal Analysis

impurities

-

mp

682 °C (lit.)

mp

682 °C (lit.)

mp

682 °C (lit.)

mp

682 °C (lit.)

solubility

H2O: 3 M at 20 °C, clear, colorless

solubility

methanol: slightly soluble(lit.), pyridine: insoluble(lit.)

solubility

methanol: slightly soluble(lit.), pyridine: insoluble(lit.)

solubility

-

assay

≥99.0% (F)

assay

99.99% trace metals basis

assay

99.99% trace metals basis

assay

≥98.0%

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

grade

reagent grade

grade

-

grade

-

grade

-

impurities

insoluble matter, passes filter test, ≤0.005% total nitrogen (N)

impurities

≤150.0 ppm Trace Metal Analysis

impurities

≤150.0 ppm Trace Metal Analysis

impurities

-

mp

682 °C (lit.)

mp

682 °C (lit.)

mp

682 °C (lit.)

mp

682 °C (lit.)


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Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Repr. 2 - STOT RE 2

target_organs

Kidney,Adrenal gland

supp_hazards

Storage Class

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges



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Jonathan L Sessler et al.
Journal of the American Chemical Society, 130(39), 13162-13166 (2008-09-09)
An ion-pair receptor, 1, containing both cation- and anion-recognizing sites, has been synthesized and characterized. Single-crystal X-ray diffraction structural studies and (1)H NMR spectroscopic analyses confirmed that 1 forms stable 1:1 complexes with CsF in solution and in the solid
B Tabakoff et al.
The New England journal of medicine, 318(3), 134-139 (1988-01-21)
Blood platelets are an accessible tissue that reflects the activity of many enzymes found in the brain. To investigate the possible effect on such enzymes of long-term consumption of large quantities of ethanol, we assayed the activities of two enzymes
Katsushi Kitahara et al.
Organic letters, 10(11), 2259-2261 (2008-05-01)
A variety of oximes were synthesized from the corresponding alcohols, alkyl halides, or alkyl sulfonates without using external oxidants. With this simple two-step procedure involving substitution with readily available TsNHOTBS and subsequent treatment with CsF, a range of oximes were



Global Trade Item Number

SKUGTIN
20989-250G04061833440094
20989-10G04061838770967

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