Passa al contenuto
Merck

205273

Isopropossido di titanio (IV)

97%

Sinonimo/i:

TTIP, Ortotitanato di tetraisopropile

Autenticati per visualizzare i prezzi organizzativi e contrattuali.

Scegli un formato

Prezzi e disponibilità al momento non sono disponibili

Informazioni su questo articolo

Formula condensata:
Ti[OCH(CH3)2]4
Numero CAS:
Peso molecolare:
284.22
UNSPSC Code:
12352106
NACRES:
NA.22
PubChem Substance ID:
EC Number:
208-909-6
Beilstein/REAXYS Number:
3679474
MDL number:

Vai a

Servizio Tecnico
Hai bisogno di aiuto? Il nostro team di scienziati qualificati è a tua disposizione.
Permettici di aiutarti

Nome del prodotto

Isopropossido di titanio (IV), 97%

InChI key

VXUYXOFXAQZZMF-UHFFFAOYSA-N

InChI

1S/4C3H7O.Ti/c4*1-3(2)4;/h4*3H,1-2H3;/q4*-1;+4

SMILES string

CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C

assay

97%

form

liquid

reaction suitability

core: titanium
reagent type: catalyst

refractive index

n20/D 1.464 (lit.)

bp

232 °C (lit.)

mp

14-17 °C (lit.)

density

0.96 g/mL at 20 °C (lit.)

Quality Level

Cerchi prodotti simili? Visita Guida al confronto tra prodotti

Confronta articoli simili

Visualizza il confronto per intero

Mostra le differenze

1 of 4

Questo articolo
87560377996687502
assay

97%

assay

≥97.0%

assay

99.999% trace metals basis

assay

99.999%

reaction suitability

core: titanium, reagent type: catalyst

reaction suitability

core: titanium, reagent type: Lewis acid, reagent type: catalyst

reaction suitability

core: titanium, reagent type: catalyst

reaction suitability

core: titanium, reagent type: catalyst

form

liquid

form

liquid

form

liquid

form

liquid

Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

100

mp

14-17 °C (lit.)

mp

14-17 °C (lit.)

mp

14-17 °C (lit.)

mp

14-17 °C (lit.)

bp

232 °C (lit.)

bp

232 °C (lit.)

bp

232 °C (lit.)

bp

232 °C (lit.)

Application

Comunemente utilizzato come precursore per la preparazione del biossido di titanio (TiO2)[1][2]
Nuovi ibridi di ossido di metallo/fosfonato sono stati prodotti a partire da isopropossido di titanio (IV) in un processo sol-gel a due fasi. Materiale di partenza per film sottili di titanato di bario-stronzio. Utilizzato per produrre titanosilicati porosi, come potenziali materiali di scambio ionico per lo smaltimento dei rifiuti radioattivi. Usato nella formazione di un'eterosupermolecola costituita da un complesso accettore di elettroni di nanocristallito di TiO2 -viologeno di cui è stato dimostrato il trasferimento di elettroni indotto dalla luce.

General description

L'isopropossido di titanio(IV) è un composto di coordinazione a base di titanio, comunemente usato nella reazione di epossidazione di Sharpless asimmetrica di alcoli allilici. È anche usato come catalizzatore nella reazione di Kulinkovich per la sintesi di ciclopropani.[3][4][5]

Legal Information

Prodotto da Dorf Ketal
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Packaging

Il flacone da 25 mL Sure/Seal è specificato monouso. Ripetute perforazioni potrebbero causare una riduzione delle prestazioni del prodotto.

pictograms

FlameExclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - STOT SE 3

target_organs

Central nervous system

Classe di stoccaggio

3 - Flammable liquids

wgk

WGK 1

flash_point_f

105.8 °F - Pensky-Martens closed cup

flash_point_c

41 °C - Pensky-Martens closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


Scegli una delle versioni più recenti:

Certificati d'analisi (COA)

Lot/Batch Number

Non trovi la versione di tuo interesse?

Se hai bisogno di una versione specifica, puoi cercare il certificato tramite il numero di lotto.

Possiedi già questo prodotto?

I documenti relativi ai prodotti acquistati recentemente sono disponibili nell’Archivio dei documenti.

Visita l’Archivio dei documenti

Asymmetric epoxidation of allylic alcohols: the Katsuki-Sharpless epoxidation reaction
Katsuki T and Martin V
Organic Reactions, 48(3), 1-299 (2004)
Al-Jufairi, N.
Materials Science Forum, 517, 165-172 (2006)
Titanium (IV) isopropoxide-catalyzed formation of 1-substituted cyclopropanols in the reaction of ethylmagnesium bromide with methyl alkanecarboxylates
Kulinkovich OG, et al.
Synthesis, 3, 234-234 (1991)
Ethers, Epoxides, and Sulfides
Organic Chemistry (2008)
J A Darr et al.
IEE proceedings. Nanobiotechnology, 152(3), 109-111 (2006-01-31)
Surfactant-coated amorphous titania nanospheres have been synthesised using templating 'water-in-supercritical carbon dioxide' emulsion droplets; the process represents a clean and controlled method for the manufacture of high-purity nanoparticles.

Articoli

Few Monolayer Atomic Layer Deposition (ALD) on Surfaces and Interfaces for Energy Applications

Titanium dioxide applications: Semiconducting material characteristics and diverse functionalities.

Electrospinning technique applications discussed, emphasizing control of nanofibers and assembly into 3D architectures.

Questions

1–9 of 9 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. Buongiorno, utilizziamo questo reagente per determinare la presenza di acqua nei solventi acquistati. Sapreste dirmi qual è la quantità minima di acqua che è possibile rilevare?

    1 answer
    1. While this material will react with water to form TiO2, the product is not specifically tested or used as a water scavenger. Unfortunately, there is no internal method or information available regarding this reaction. A brief search of the literature did not reveal any additional information.

      Helpful?

  4. What is the equivalent weight of ttip

    1 answer
    1. The equivalent weight of this product can be calculated by dividing the molecular weight by the net positive valence. It has 284.22 grams of Titanium(IV) isopropoxide per mole of titanium, and 71.055 grams of Titanium(IV) isopropoxide per mole of isopropoxide. The equivalent weight would depend on the source. That is, if you are looking at the material as a source of Titanium(IV), you would use 284.22 grams. But if they are looking at it as a source of the strong base (isopropoxide ion), you would use 71.055 grams. When looking at the Titanium(IV) isopropoxide per mole of titanium, there are +4 positively charged valence electrons which resulted 71.055 for the equivalent weight.

      Helpful?

  5. What is the difference between this and 87560 ttip?

    1 answer
    1. Products 205273 and 87560 have the same Chemical Abstract Service (CAS) number
      546-68-9, which means chemically they are the same substance. The difference between the two products are the product specifications. The product specification sheets for each product are linked below to facilitate a comparison for the specific application needs.

      https://www.sigmaaldrich.com/specification-sheet/ALDRICH/87560
      https://www.sigmaaldrich.com/specification-sheets/355/956/205273-BULK.pdf

      Helpful?

  6. What is the viscosity of Product 205273, Titanium (IV) Isopropoxide?

    1 answer
    1. The viscosity of titanium (IV) isopropoxide is 4.5 centipoise at 25 deg C.

      Helpful?

  7. What is the Department of Transportation shipping information for this product?

    1 answer
    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

      Helpful?

  8. What needs to be done if Product 205273, Titanium (IV) Isopropoxide is a solid instead of a liquid?

    1 answer
    1. The material will melt/freeze at 18-20 deg C, therefore the material can freeze when shipped during the winter months.  It can be warmed in a water bath to about 30 deg C to change the state without harming the chemical.

      Helpful?

  9. What is Product 205273, Titanium (IV) Isopropoxide soluble in?

    1 answer
    1. This chemical is very soluble in ethanol, carbon tetrachloride, hexane, benzene, or isopropanol.  Water is not recommended as a solvent because titanium (IV) isopropoxide will hydrolyze. (Precautions should be taken to make sure the solvents used do not contain any water - anhydrous grades would be recommended).

      Helpful?

Reviews

No rating value

Active Filters

Il team dei nostri ricercatori vanta grande esperienza in tutte le aree della ricerca quali Life Science, scienza dei materiali, sintesi chimica, cromatografia, discipline analitiche, ecc..

Contatta l'Assistenza Tecnica