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Merck

215473

硝酸铈(IV)铵

ACS reagent, ≥98.5%

同義詞:

硝酸铈铵

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關於此項目

線性公式:
Ce(NH4)2(NO3)6
CAS 編號:
分子量::
548.22
EC號碼:
MDL號碼:
分類程式碼代碼:
12352302
PubChem物質ID:
NACRES:
NB.24

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等級

ACS reagent

化驗

≥98.5%

形狀

powder or crystals

反應適用性

reagent type: oxidant

雜質

≤0.05% insol. dil. H2SO4

負離子痕跡

chloride (Cl-): ≤0.01%
phosphate (PO43-): ≤0.02%

正離子痕跡

Fe: ≤0.005%

SMILES 字串

N.N.[Ce+4].O[N+]([O-])=O.O[N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/Ce.2HNO3.4NO3.2H3N/c;6*2-1(3)4;;/h;2*(H,2,3,4);;;;;2*1H3/q+4;;;4*-1;;

InChI 密鑰

WIBGOERAEYJBOT-UHFFFAOYSA-N

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1 of 4

本產品
222491.02276C3654
form

powder or crystals

form

powder or crystals

form

crystalline

form

powder or crystals

assay

≥98.5%

assay

≥98.5% (RT)

assay

≥99.0% ((NH4)2[Ce(NO3)6] basis, potentiometry)

assay

≥98% (titration)

Quality Level

200

Quality Level

200

Quality Level

300

Quality Level

100

grade

ACS reagent

grade

ACS reagent, puriss. p.a.

grade

ACS reagent

grade

-

impurities

≤0.05% insol. dil. H2SO4

impurities

-

impurities

≤0.005% Substances insoluble in diluted sulfuric acid

impurities

-

cation traces

Fe: ≤0.005%

cation traces

Ca: ≤10 mg/kg, Cd: ≤5 mg/kg, Co: ≤5 mg/kg, Cr: ≤5 mg/kg, Cu: ≤5 mg/kg, Fe: ≤50 mg/kg, K: ≤10 mg/kg, Mg: ≤20 mg/kg, Mn: ≤5 mg/kg, Na: ≤100 mg/kg, Ni: ≤5 mg/kg, Pb: ≤5 mg/kg, Zn: ≤5 mg/kg

cation traces

Fe: ≤0.003%, Na: ≤0.005%, heavy metals (as Pb): ≤0.002%

cation traces

-

應用

提供通过温和条件下氧化丙二酸盐得到丙醇二酸衍生物的一种新途径。[1]

訊號詞

Danger

危險分類

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Ox. Sol. 2 - Skin Corr. 1B - Skin Sens. 1A

儲存類別代碼

5.1B - Oxidizing hazardous materials

水污染物質分類(WGK)

WGK 3


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分析證明 (COA)

Lot/Batch Number

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您可以在文件庫中找到最近購買的產品相關文件。

存取文件庫

Carbon-heteroatom bond-forming reactions mediated by cerium (IV) ammonium nitrate: An overview.
Nair V, et al.
Synlett, 14(2), 156-165 (2003)
Selective and efficient oxidation of sulfides to sulfoxides using ammonium cerium (IV) nitrate in the presence of a catalytic amount of KBr or NaBr.
Zolfigol MA, et al.
Monatshefte fur Chemie / Chemical Monthly, 139(8), 895--895- (2008)
A New. ALPHA.-Iodination of Ketones Using Iodine-Ammonium Cerium (IV) Nitrate in Alcohol or Acetic Acid.
Horiuchi CA and Kiji S.
Bulletin of the Chemical Society of Japan, 70(2), 421-426 (1997)
Cerium (IV) ammonium nitrate (CAN) as a catalyst in tap water: A simple, proficient and green approach for the synthesis of quinoxalines.
More SV, et al.
Green Chemistry, 8(1), 91-95 (2006)
Polyethylene glycol (PEG) mediated green synthesis of 2, 5-disubstituted 1, 3, 4-oxadiazoles catalyzed by ceric ammonium nitrate (CAN).
Kidwai M, et al.
Green Chemistry Letters and Reviews, 31(1), 55-59 (2010)

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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