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MilliporeSigma

802425

2-Bromo-1,10-phenanthroline

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About This Item

Empirical Formula (Hill Notation):
C12H7BrN2
CAS Number:
22426-14-8
Molecular Weight:
259.10
MDL number:
MFCD13152102
UNSPSC Code:
12352100
PubChem Substance ID:
329768737
NACRES:
NA.22

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form

powder

Quality Level

100

mp

160-165 °C

functional group

bromo

SMILES string

BrC1=NC2=C(N=CC=C3)C3=CC=C2C=C1

InChI

1S/C12H7BrN2/c13-10-6-5-9-4-3-8-2-1-7-14-11(8)12(9)15-10/h1-7H

InChI key

ZRJUDAZGVGIDLP-UHFFFAOYSA-N

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1 of 4

This Item
301817678015301779
2-Bromo-1,10-phenanthroline

Sigma-Aldrich

802425

2-Bromo-1,10-phenanthroline

5,6-Dimethyl-1,10-phenanthroline 97%

Sigma-Aldrich

301817

5,6-Dimethyl-1,10-phenanthroline

4,7-Dichloro-1,10-phenanthroline 97%

Sigma-Aldrich

678015

4,7-Dichloro-1,10-phenanthroline

5-Chloro-1,10-phenanthroline 98%

Sigma-Aldrich

301779

5-Chloro-1,10-phenanthroline

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

mp

160-165 °C

mp

266-269 °C (lit.)

mp

243-247 °C

mp

124-126 °C (lit.)

form

powder

form

-

form

solid

form

-

functional group

bromo

functional group

-

functional group

-

functional group

chloro

Application

Brominated phenanthroline can be synthesized via a method reported by Baran and coworkers using a two-step protocol through N-Oxide formation using m-CBPA (Aldrich 273031) and bromination using TBAB (Sigma-Aldrich 426288) and p-Toluenesulfonic anhydride (Aldrich 259764).

Other Notes

Regioselective Bromination of Fused Heterocyclic N-Oxides

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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