Skip to Content
MilliporeSigma

Skip To

224448

Phenylmagnesium chloride solution

2.0 M in THF

Synonym(s):

Chlorophenylmagnesium

Sign In to View Organizational & Contract Pricing.

Select a Size

Change View
Size/SKUAvailabilityPrice
100 mL

Available to ship TODAY

$97.40
$82.79
800 mL

Available to ship TODAY

$320.00
$240.00
8 L
Check Cart for Availability
$2,830.00
18 L
Check Cart for Availability
$5,420.00

About This Item

Linear Formula:
C6H5MgCl
CAS Number:
Molecular Weight:
136.86
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3587900
eCl@ss:
32129103

$82.79

List Price$97.40Save 15%
Web-Only Discount

Available to ship TODAYDetails


​
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist


Quality Segment

reaction suitability

reaction type: Grignard Reaction

packaging

Kilo-Lab™ of , Sure/Seal™ of

concentration

2.0 M in THF

density

~1.02 g/mL at 20 °C, 1.042 g/mL at 25 °C

SMILES string

Cl[Mg]c1ccccc1

InChI

1S/C6H5.ClH.Mg/c1-2-4-6-5-3-1;;/h1-5H;1H;/q;;+1/p-1

InChI key

GQONLASZRVFGHI-UHFFFAOYSA-M

Application

Phenylmagnesium chloride (PhMgCl) solution is a common Grignard reagent used in the synthesis of (−)-phenserine and stephacidin B. It is employed in a variety of cross-coupling reactions. It can also be used as an electrolyte solution along with aluminium chloride (AlCl3) in the rechargeable magnesium batteries.

Other Notes

Storage below 25°C may cause formation of crystalline magnesium salts. Moving container to a warm location and occasional gentle swirling should redissolve the solid

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
Kilo-Lab is a trademark of Merck KGaA, Darmstadt, Germany

Compare Similar Items

View Full Comparison

Show Differences

1 of 1

This Item
257125171565774448
description

2.0 M in THF

description

2.0 M in THF

description

3.0 M in diethyl ether

description

1.0 M in 2-methyltetrahydrofuran

reaction suitability

reaction type: Grignard Reaction

reaction suitability

reaction type: Grignard Reaction

reaction suitability

reaction type: Grignard Reaction

reaction suitability

reaction type: Grignard Reaction

density

~1.02 g/mL at 20 °C, 1.042 g/mL at 25 °C

density

~1.02 g/mL at 20 °C, 1.042 g/mL at 25 °C

density

1.134 g/mL at 25 °C

density

1.005 g/mL at 25 °C

Quality Level

200

Quality Level

100

Quality Level

200

Quality Level

100

concentration

2.0 M in THF

concentration

2.0 M in THF

concentration

3.0 M in diethyl ether

concentration

1.0 M in 2-methyltetrahydrofuran

packaging

Sure/Seal™ of , Kilo-Lab™ of

packaging

Sure/Pac™ of

packaging

Kilo-Lab™ of , Sure/Seal™ of

packaging

Sure/Seal™ of


Still not finding the right product?

Explore all of our products under Phenylmagnesium chloride solution


Signal Word

Danger

Hazard Classifications

Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

Target Organs

Central nervous system, Respiratory system

supp_hazards

Storage Class

3 - Flammable liquids

Flash Point (°F)

1.4 °F - closed cup

Flash Point (°C)

-17 °C - closed cup

PPE (personal protective equipment)

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter



Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

It looks like we've run into a problem, but you can still download Certificates of Analysis from our Documents section.

If you need assistance, please contact Customer Support

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library



Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

Reviews

No rating value

Active Filters