If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
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For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
346152
Ethynylmagnesium bromide solution
0.5 M in THF
Synonym(s):
Acetylenemagnesium bromide, Bromoethynylmagnesium, Ethynylmagnesium bromide
Select a Size
| Size/SKU | Availability | Price |
|---|---|---|
100 mL | Available to ship TODAYfromMILWAUKEE | $84.70 |
800 mL | Available to ship TODAYfromMILWAUKEE | $363.00 |
About This Item
Quality Segment
reaction suitability
reaction type: Grignard Reaction
packaging
Sure/Seal™ of
concentration
0.5 M in THF
density
0.94 g/mL at 25 °C
storage temp.
2-8°C
SMILES string
Br[Mg]C#C
InChI
1S/C2H.BrH.Mg/c1-2;;/h1H;1H;/q;;+1/p-1
InChI key
HUGJUYPSXULVQQ-UHFFFAOYSA-M
General description
Application
- Grafting of aliphatic polymer.
- Synthesis of anthracene-containing species like 1,8-dichloro-10-(ethynyl)anthracene.
- The preparation of the alkyne component in an enyne cross-metathesis leading to conjugated dienes.
- Ethynylation of chiral α-(dibenzylamino) aldehydes.
- The synthesis of ethynyl aziridines.
- To prepare alkyl(triethynyl)germanes from tert-alkyltrichlorogermanes and 2-butyltrichlorogermane.
- The preperation of a key intermediate in the total synthesis of (+)-4-demethoxydaunomycin.
Legal Information
1 of 1
This Item | |||
|---|---|---|---|
| description 0.5 M in THF | description 0.75 M in THF | description 0.5 M in THF | description 0.5 M in THF |
| reaction suitability reaction type: Grignard Reaction | reaction suitability reaction type: Grignard Reaction | reaction suitability reaction type: Grignard Reaction | reaction suitability reaction type: Grignard Reaction |
| concentration 0.5 M in THF | concentration 0.75 M in THF | concentration 0.5 M in THF | concentration 0.5 M in THF |
| density 0.94 g/mL at 25 °C | density 0.982 g/mL at 25 °C | density 0.952 g/mL at 25 °C | density 0.955 g/mL at 25 °C |
| Quality Level 200 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
| storage temp. 2-8°C | storage temp. 2-8°C | storage temp. - | storage temp. - |
| packaging Sure/Seal™ of | packaging Sure/Seal™ of | packaging Sure/Seal™ of | packaging Sure/Seal™ of |
Signal Word
Danger
Hazard Codes
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react. 2
Target Organs
Central nervous system, Respiratory system
supp_hazards
Storage Class
4.3 - Hazardous materials which set free flammable gases upon contact with water
Flash Point (°F)
-20.2 °F
Flash Point (°C)
-29 °C
PPE (personal protective equipment)
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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