If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
393290
Tris(dimethylamino)phosphine
97%, liquid
Synonym(s):
(Me2N)3P, Hexamethyltriamidophosphite, Hexamethyltriaminophosphine, HMPT, Hexamethylphosphorous triamide
Select a Size
| Size/SKU | Availability | Price |
|---|---|---|
5 mL | Available to ship TODAY | $82.30 |
25 mL | Available to ship TODAY | $330.00 |
About This Item
$82.30
Available to ship TODAYDetails
Product Name
Tris(dimethylamino)phosphine, 97%
Quality Segment
assay
97%
form
liquid
reaction suitability
reagent type: ligand
reaction type: Reductions, reagent type: ligand
reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
reaction type: Wittig Reaction
refractive index
n20/D 1.463 (lit.)
bp
48-50 °C/12 mmHg (lit.)
density
0.898 g/mL at 25 °C (lit.)
functional group
phosphine
SMILES string
CN(C)P(N(C)C)N(C)C
InChI
1S/C6H18N3P/c1-7(2)10(8(3)4)9(5)6/h1-6H3
InChI key
XVDBWWRIXBMVJV-UHFFFAOYSA-N
Application
- Ligand in the preparation of arene-ruthenium(II) complex which is used as a catalyst in hydration of nitriles to amides.
- Phosphorus source along with InCl3 in the synthesis of InP colloidal quantum dots (QDs).
- Deoxygenating agent for some α-dicarbonyl compounds in the presence of fullerene C60.
Signal Word
Danger
Hazard Codes
Precautionary Statements
Hazard Classifications
Carc. 1B - Eye Irrit. 2 - Flam. Liq. 3 - Muta. 1B - Skin Irrit. 2
Storage Class
3 - Flammable liquids
Flash Point (°F)
80.6 °F - closed cup
Flash Point (°C)
27 °C - closed cup
PPE (personal protective equipment)
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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