If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
703540
2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution
1.0 M in THF
Synonym(s):
TMPMgCl·LiCl
Select a Size
| Size/SKU | Availability | Price |
|---|---|---|
100 mL | Check Cart for Availability | $237.00 |
4 x 25 mL | Check Cart for Availability | $239.00 |
500 mL | Check Cart for Availability | $733.00 |
About This Item
form
liquid
Quality Segment
reaction suitability
reaction type: Grignard Reaction
packaging
Sure/Seal™ of
concentration
1.0 M in THF, 20 % (w/w)
density
0.96 g/mL at 25 °C
storage temp.
2-8°C
SMILES string
[Li+].[Cl-].CC1(C)CCCC(C)(C)N1[Mg]Cl
InChI
1S/C9H18N.2ClH.Li.Mg/c1-8(2)6-5-7-9(3,4)10-8;;;;/h5-7H2,1-4H3;2*1H;;/q-1;;;+1;+2/p-2
InChI key
JHBZAAACZVPPRQ-UHFFFAOYSA-L
Application
Packaging
Legal Information
1 of 1
This Item | |||
|---|---|---|---|
| description 1.0 M in THF | description 1.3 M in THF | description 0.5 M in benzene: cyclohexane | description 1.5 M in diethyl ether |
| reaction suitability reaction type: Grignard Reaction | reaction suitability reaction type: Grignard Reaction | reaction suitability - | reaction suitability - |
| Quality Level 100 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
| concentration 20 % (w/w), 1.0 M in THF | concentration 1.3 M in THF | concentration 0.5 M in benzene: cyclohexane | concentration 1.5 M in diethyl ether |
| density 0.96 g/mL at 25 °C | density 0.951 g/mL at 25 °C | density 0.862 g/mL at 25 °C | density 0.852 g/mL at 25 °C |
| storage temp. 2-8°C | storage temp. - | storage temp. 2-8°C | storage temp. 2-8°C |
| packaging Sure/Seal™ of | packaging Sure/Seal™ of | packaging - | packaging - |
Signal Word
Danger
supp_hazards
Storage Class
3 - Flammable liquids
Flash Point (°F)
5.0 °F
Flash Point (°C)
-15 °C
Hazard Codes
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
Target Organs
Central nervous system, Respiratory system
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How can I determine the shelf life / expiration / retest date of this product?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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