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D28000

Diazald®

99%

Synonym(s):

N-Methyl-N-(p-tolylsulfonyl)nitrosamide, N-Methyl-N-nitroso-p-toluenesulfonamide, N-Nitroso-N-methyl-p-toluenesulfonamide, N-Nitroso-p-toluenesulfomethylamide, p-Tolylsulfomethylnitrosamide, Diazomethane precursor

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Size/SKUAvailabilityPrice
25 g
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$56.10

About This Item

Linear Formula:
CH3C6H4SO2N(CH3)NO
CAS Number:
Molecular Weight:
214.24
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
EC Number:
201-252-6
Beilstein/REAXYS Number:
2214345
MDL number:
Assay:
99%
Form:
solid

$56.10


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Quality Segment

assay

99%

form

solid

reaction suitability

reaction type: Halogenations

mp

61-62 °C (lit.)

SMILES string

CN(N=O)S(=O)(=O)c1ccc(C)cc1

InChI

1S/C8H10N2O3S/c1-7-3-5-8(6-4-7)14(12,13)10(2)9-11/h3-6H,1-2H3

InChI key

FFKZOUIEAHOBHW-UHFFFAOYSA-N

Application

Nitrosylating agent for transition metal complexes, amines, and carbanions, as well as a precursor to diazomethane.

Preparation Note

Warning: these products are subject to the Explosives Act and must be transported refrigerated - additional costs for transport will apply.

Legal Information

Diazald is a registered trademark of Merck KGaA, Darmstadt, Germany

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This Item
Z100250Z115584Z100390
description

99%

description

joint: ST/NS 19/22

description

joint: ST/NS 24/40

description

joint: ST/NS 19/22

assay

99%

assay

-

assay

-

assay

-

reaction suitability

reaction type: Halogenations

reaction suitability

-

reaction suitability

-

reaction suitability

-

Quality Level

200

Quality Level

-

Quality Level

-

Quality Level

-

form

solid

form

-

form

-

form

-

mp

61-62 °C (lit.)

mp

-

mp

-

mp

-

Diazald reagent

-

-

-


Pictograms

FlameExclamation mark

Signal Word

Danger

Hazard Classifications

Eye Irrit. 2 - Self-react. C - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Target Organs

Respiratory system

Storage Class

4.1A - Other explosive hazardous materials

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

PPE (personal protective equipment)

dust mask type N95 (US), Eyeshields, Faceshields, Gloves



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Questions

1–6 of 6 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. Can Product D28000, Diazald®, be used in mutagenesis studies?

    1 answer
    1. Product D28000 (Diazald®) is the suggested alternative for MNNG (1-methyl-3-nitroso-1-nitroguanidine), which has been used for mutagenesis experiments. Unfortunately, Sigma-Aldrich has not tested the affect of Diazald® as a mutagenic agent. It is structurally distinct from MNNG. Products N4766 and N1517 (N-nitroso-N-methylurea), which are recommended for work in mutagenesis, might be more suitable alternatives than product D28000.

      Helpful?

  4. What solvents can be used to dissolve Product D28000, Diazald®?

    1 answer
    1. According to the 13th edition of the chemicals encyclopedia published by the Royal Society of Chemistry, it is soluble in ether, petroleum ether, benzene, chloroform, carbon tetrachloride. It is also soluble in ethanol.

      Helpful?

  5. Is Diazald, Product No. D28000 product light-, moisture-, or heat-sensitive?

    1 answer
    1. Per the MSDS, this product is light- and heat-sensitive. It may decompose and ignite when stored at a temperature above 40oC.

      Helpful?

  6. What is the Department of Transportation shipping information for this product?

    1 answer
    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

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