The solubility of this product has not been determined. However, in certain reactions, such as hydrogenation, ethanol is typically utilized. Note that palladium on carbon (Pd/C) is a heterogeneous catalyst that is insoluble in water and many common organic solvents.
205699
Palladium on carbon
Greener Alternative
extent of labeling: 10 wt. % loading, matrix activated carbon support, powder
Synonym(s):
Pd/C
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| Size/SKU | Availability | Price |
|---|---|---|
1 g | Available to ship TODAYfromMILWAUKEE | $38.30 |
10 g | Available to ship TODAYfromMILWAUKEE | $248.00 |
50 g | Available to ship TODAYfromMILWAUKEE | $1,110.00 |
250 g | Available to ship TODAYfromMILWAUKEE | $5,100.00 $4,335.00 |
About This Item
Linear Formula:
Pd
Molecular Weight:
106.42
UNSPSC Code:
12141733
eCl@ss:
38191001
PubChem Substance ID:
NACRES:
NA.22
MDL number:
$38.30
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Product Name
Palladium on carbon, extent of labeling: 10 wt. % loading, matrix activated carbon support
form
powder
Quality Segment
reaction suitability
core: palladium, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Buchwald-Hartwig Cross Coupling Reaction
greener alternative product characteristics
Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
extent of labeling
10 wt. % loading
matrix
activated carbon support
greener alternative category
SMILES string
[Pd]
InChI
1S/Pd
InChI key
KDLHZDBZIXYQEI-UHFFFAOYSA-N
General description
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.
Application
Catalyst for:
- Stille reaction
- Hydrogenation reactions
- Suzuki-Miyaura cross-coupling and Heck-Mizoroki reactions
- Deoxygenation
- Oxidation reactions
- Coupling reactions
Palladium on carbon (Pd/C) (10 wt. % loading, matrix activated carbon support) can be used as a catalyst in the well known reactions like hydrogenation of alkenes, alkynes, ketones, nitriles, imines, azides, nitro groups, benzenoid and heterocyclic aromatics; hydrogenolysis of cyclopropanes, benzyl derivatives, epoxides, hydrazines, and halides; dehydrogenate aromatics and deformylate aldehydes.
It can also be used as:
It can also be used as:
- A catalyst for hydrodechlorination of dichlorodifluoromethane (CCl2F2), which is a known greenhouse gas,
- A catalyst for Heck reactions of aryl halides in ionic liquids
- An anode catalyst for the fabrication of direct formic acid fuel cells (DFAFC)
- A cost-effective electrocatalyst for the oxidation of methanol
- In the catalytic hydrogenation of chemical hydrides for the production of hydrogen
- A catalyst in Suzuki-Mayaura reaction
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This Item | |||
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| description extent of labeling: 10 wt. % loading, matrix activated carbon support | description extent of labeling: 5 wt. % loading (dry basis), matrix activated carbon support | description extent of labeling: 1 wt. % loading, matrix activated carbon support | description extent of labeling: 3 wt. % loading, matrix activated carbon support |
| reaction suitability core: palladium, reaction type: Hiyama Coupling, reaction type: Sonogashira Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: Negishi Coupling, reagent type: catalyst | reaction suitability core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst | reaction suitability core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst | reaction suitability core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst |
| form powder | form powder | form powder | form powder |
| Quality Level 200 | Quality Level 200 | Quality Level 100 | Quality Level 100 |
| sustainability Greener Alternative Product | sustainability Greener Alternative Product | sustainability Greener Alternative Product | sustainability Greener Alternative Product |
| matrix activated carbon support | matrix activated carbon support | matrix activated carbon support | matrix activated carbon support |
| extent of labeling 10 wt. % loading | extent of labeling 5 wt. % loading (dry basis) | extent of labeling 1 wt. % loading | extent of labeling 3 wt. % loading |
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Storage Class
11 - Combustible Solids
flash_point_f
Not applicable
flash_point_c
Not applicable
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Which solvents are suitable for dispersing this material (e.g., water, alcohols, or other organic solvents) ?
1 answer-
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What is the density of product 205699.
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The density of this product is not determined.
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How can I determine the shelf life / expiration / retest date of this product?
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If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdfHelpful?
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How is shipping temperature determined? And how is it related to the product storage temperature?
1 answer-
Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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How much is the palladium on carbon
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This product is 10 wt.% Palladium on activated carbon support.
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We are using this catalyst in our work. Do you have a particle distribution range for the activated carbon used?
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Unfortunately, based on the specification sheet for Product 205699, a specification for the particle distribution range is not tested. This information is unavailable.
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I wanted to ask how activated carbon was loaded with Pd. I appreciate if you could provide the preparation method.
1 answer-
This product is an M-Clarity level 200 item. The method of preparation is considered proprietary for Products of this level.
However, you may find it helpful to read this article:
https://www.masterorganicchemistry.com/2011/11/25/palladium-on-carbon-pdc/Helpful?
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What is the particle size of Product 205699, Palladium on carbon?
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We expect the product to conform to the following: approximately 90% <60 μm and 10% <5 μm with an average particle size of 15 μm.
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What is the surface area of Product 205699, Palladium on carbon?
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The surface area of the carbon used as the support is 750-1000 m2 /g. They do not test the surface area of the finished catalyst.
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What is the activity of Product 205699, Palladium on carbon? How is the activity tested? Is it a guaranteed value?
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There is a fairly large variance in activity reported by the manufacturer on this material (from less than 50 ml/min to more than 100 ml/min). Activity is not a specification but reported on the Certification of Analysis for further information. Activity is measured by the hydrogen reduction of nitrobenzene.
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