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209015

Palladium(II) acetylacetonate

99%

Synonym(s):

Palladium(II) 2,4-pentanedionate, Pd(acac)2

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1 g

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$115.00
$97.75
5 g

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$451.00

About This Item

Linear Formula:
Pd(C5H7O2)2
CAS Number:
Molecular Weight:
304.64
UNSPSC Code:
12352103
NACRES:
NA.23
PubChem Substance ID:
EC Number:
237-859-8
Beilstein/REAXYS Number:
4136188
MDL number:

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Quality Segment

assay

99%

form

powder

reaction suitability

core: aluminum, reagent type: catalyst

mp

200-251 °C (dec.)

SMILES string

CC(=O)\C=C(\C)O[Pd]O\C(C)=C/C(C)=O

InChI

1S/2C5H8O2.Pd/c2*1-4(6)3-5(2)7;/h2*3,6H,1-2H3;/q;;+2/p-2/b2*4-3-;

InChI key

JKDRQYIYVJVOPF-FDGPNNRMSA-L

General description

Palladium(II) acetylacetonate (Pd(acac)2) is a metal-organic complex. Sublimation of Pd(acac)2 has been investigated by thermogravimetry and XRD. The temperature range for the sublimation of Pd(acac)2, without undergoing thermal decomposition, was determined to be 100-160°C in the presence of inert gas helium.

Application

Palladium(II) acetylacetonate (Pd(acac)2) was used in the following studies:
  • Typical high-temperature organic solution phase protocol for the preparation of monodisperse CuPd alloy nanoparticles (NPs).
  • Preparation of [(NHC)Pd(acac)L] (where L=Me, NHC = N-heterocyclic carbene) complexes. These complexes efficiently catalyze the Heck reaction of activated aryl bromides.
  • As catalyst in the decarboxylative cross-coupling of arylcarboxylic acids with aryl halides.

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This Item
921025401684I3300
description

99%

description

≥99.9% trace metals basis

description

technical grade

description

≥99.99% trace metals basis

form

powder

form

-

form

powder

form

(powder or solid or crystals)

assay

99%

assay

≥99.9% trace metals basis

assay

-

assay

≥99.99% trace metals basis

mp

200-251 °C (dec.)

mp

200-251 °C (dec.)

mp

141-144 °C (lit.)

mp

187-189 °C (lit.)

reaction suitability

reagent type: catalyst, core: aluminum

reaction suitability

core: palladium

reaction suitability

reagent type: catalyst, core: lead

reaction suitability

core: indium, reagent type: catalyst

Quality Level

100

Quality Level

200

Quality Level

100

Quality Level

100


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Pictograms

Exclamation mark

Signal Word

Warning

Hazard Codes

Hazard Classifications

Eye Irrit. 2

Storage Class

11 - Combustible Solids

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

PPE (personal protective equipment)

dust mask type N95 (US), Eyeshields, Gloves



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Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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