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27096

Chromium(III) chloride hexahydrate

≥98.0% (RT), solid, purum p.a.

Synonym(s):

Chromium trichloride hexahydrate, Hexaaquachromium(III) chloride

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100 g

Available to ship TODAY

$34.50
500 g

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$161.00
1 kg

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$188.00

About This Item

Linear Formula:
CrCl3 · 6H2O
CAS Number:
Molecular Weight:
266.45
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
233-038-3
MDL number:

$34.50


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Product Name

Chromium(III) chloride hexahydrate, purum p.a., ≥98.0% (RT)

grade

purum p.a.

Quality Segment

assay

≥98.0% (RT)

form

solid

reaction suitability

core: chromium, reagent type: catalyst

density

1.76 g/mL at 25 °C (lit.)

anion traces

sulfate (SO42-): ≤500 mg/kg

cation traces

Ca: ≤300 mg/kg, Cd: ≤50 mg/kg, Co: ≤50 mg/kg, Cu: ≤50 mg/kg, Fe: ≤100 mg/kg, K: ≤100 mg/kg, Na: ≤300 mg/kg, Ni: ≤50 mg/kg, Pb: ≤50 mg/kg, Zn: ≤50 mg/kg

SMILES string

[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].Cl[Cr](Cl)Cl

InChI

1S/3ClH.Cr.6H2O/h3*1H;;6*1H2/q;;;+3;;;;;;/p-3

InChI key

LJAOOBNHPFKCDR-UHFFFAOYSA-K

Application

Chromium(III) chloride (CrCl3. 6H2O) hexahydrate can be used:
  • As a source of chromium(II), which is in turn used as a catalyst in iodovinylation of aldehydes (Takai reaction).
  • In the synthesis of chromium(III) complexes of tetradentate Schiff bases.
  • In the preparation of Cr(III)-fatty acid complexes which can further be used as a catalyst for the synthesis of 1-monoacyIgIyceroIs.
  • In combination with choline chloride as a deep eutectic solvent, which can be utilized as a catalyst for the esterification of formic and acetic acid with alcohols.


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This Item
23072322300450790
description

purum p.a., ≥98.0% (RT)

description

96%

description

purum p.a., ≥98.5% (AT), ReagentPlus®

description

99.99% trace metals basis

assay

≥98.0% (RT)

assay

96%

assay

≥98.5% (AT)

assay

99.99% trace metals basis

reaction suitability

core: chromium, reagent type: catalyst

reaction suitability

reagent type: catalyst, core: chromium

reaction suitability

core: cerium, reagent type: catalyst

reaction suitability

core: chromium

form

solid

form

solid

form

crystals

form

flakes

Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

100

density

1.76 g/mL at 25 °C (lit.)

density

1.76 g/mL at 25 °C (lit.)

density

~3.94 g/mL at 25 °C (lit.)

density

2.87 g/mL at 25 °C (lit.)

cation traces

Na: ≤300 mg/kg, Cd: ≤50 mg/kg, Co: ≤50 mg/kg, Zn: ≤50 mg/kg, Ni: ≤50 mg/kg, K: ≤100 mg/kg, Pb: ≤50 mg/kg, Fe: ≤100 mg/kg, Ca: ≤300 mg/kg, Cu: ≤50 mg/kg

cation traces

-

cation traces

Co: ≤50 mg/kg, Cd: ≤50 mg/kg, Cu: ≤50 mg/kg, Ni: ≤50 mg/kg, Na: ≤100 mg/kg, K: ≤100 mg/kg, Pb: ≤50 mg/kg, Ca: ≤50 mg/kg, Fe: ≤50 mg/kg, Zn: ≤50 mg/kg

cation traces

-


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Signal Word

Warning

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2 - Met. Corr. 1 - Skin Sens. 1B

Flash Point (°F)

does not flash

Flash Point (°C)

does not flash

PPE (personal protective equipment)

dust mask type N95 (US), Eyeshields, Gloves

Storage Class

11 - Combustible Solids



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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