If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
Select a Size
| Size/SKU | Availability | Price |
|---|---|---|
5 g | Check Cart for Availability | $53.00 |
25 g | Check Cart for Availability | $169.00 |
100 g | Check Cart for Availability | $653.00 |
500 g | Check Cart for Availability | $1,200.00 |
About This Item
$53.00
grade
reagent grade
Quality Segment
vapor density
5.2 (vs air)
vapor pressure
8 mmHg ( 25 °C)
product line
ReagentPlus®
assay
≥99%
form
liquid
refractive index
n20/D 1.327 (lit.)
bp
162 °C (lit.)
mp
- 40 °C
solubility
1,600 g/L at 20 °C
density
1.696 g/mL at 25 °C (lit.)
functional group
fluoro, triflate
SMILES string
OS(=O)(=O)C(F)(F)F
InChI
1S/CHF3O3S/c2-1(3,4)8(5,6)7/h(H,5,6,7)
InChI key
ITMCEJHCFYSIIV-UHFFFAOYSA-N
General description
Application
- Substituted tetrahydrofurans and tetrahydropyrans by cyclization of corresponding unsaturated alcohols under acidic conditions.
- Nitriles from corresponding aldehydes by Schmidt reaction.
- Disubstituted five-membered ring lactones by allylboration reaction between 2-alkoxycarbonyl allylboronates and aldehydes.
It can also be used as a catalyst in the Fischer glycosylation and Friedel-Crafts acylation reactions.
Legal Information
1 of 1
This Item | ||
|---|---|---|
| description ReagentPlus®, ≥99% | description reagent grade, 98% | description 97% |
| grade reagent grade | grade reagent grade | grade - |
| assay ≥99% | assay 98% | assay 97% |
| Quality Level 200 | Quality Level 200 | Quality Level 100 |
| form liquid | form liquid | form - |
| solubility 1,600 g/L at 20 °C | solubility water: soluble 1.600 g/L at 20 °C | solubility - |
| refractive index n20/D 1.327 (lit.) | refractive index n20/D 1.327 (lit.) | refractive index - |
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Signal Word
Danger
Hazard Codes
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Met. Corr. 1 - Skin Corr. 1B - STOT SE 3
Target Organs
Respiratory system
Storage Class
8A - Combustible corrosive hazardous materials
WGK
WGK 1
PPE (personal protective equipment)
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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How can I determine the shelf life / expiration / retest date of this product?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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