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703168

cis-Bis(isothiocyanato)(2,2′-bipyridyl-4,4′-dicarboxylato)(4,4′-di-nonyl-2′-bipyridyl)ruthenium(II)

95% (NMR)

Synonym(s):

Greatcell Solar®, Z-907 dye

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About This Item

Empirical Formula (Hill Notation):
C42H52N6O4RuS2
CAS Number:
Molecular Weight:
870.10
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
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Quality Segment

assay

95% (NMR)

form

powder

composition

Dye content, ≥90%

mp

196 °C

λmax

531, 314, 295 nm (lit.)

SMILES string

S=C=N[Ru]N=C=S.OC(=O)c1ccnc(c1)-c2cc(ccn2)C(O)=O.CCCCCCCCCc3ccnc(c3)-c4cc(CCCCCCCCC)ccn4

InChI

1S/C28H44N2.C12H8N2O4.2CNS.Ru/c1-3-5-7-9-11-13-15-17-25-19-21-29-27(23-25)28-24-26(20-22-30-28)18-16-14-12-10-8-6-4-2;15-11(16)7-1-3-13-9(5-7)10-6-8(12(17)18)2-4-14-10;2*2-1-3;/h19-24H,3-18H2,1-2H3;1-6H,(H,15,16)(H,17,18);;;/q;;2*-1;+2

InChI key

LALSZYPVVQFXIC-UHFFFAOYSA-N

Application

High-performance ruthenium-based dye used in dye-sensitized solar cells (DSCs) for the sensitization of Titania. Hydrophobic character due to the presence of C9 alkyl chains.

Legal Information

Product of Greatcell Solar Materials Pty Ltd.
Greatcell Solar is a registered trademark of Greatcell Solar Materials Pty Ltd.
Greatcell Solar is a registered trademark of Greatcell Solar

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This Item
703206703214791423
description

95% (NMR)

description

-

description

95% (NMR)

description

-

form

powder

form

powder

form

powder

form

powder (maroon)

assay

95% (NMR)

assay

95% (NMR)

assay

95% (NMR)

assay

-

Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

100

composition

Dye content, ≥90%

composition

-

composition

Dye content, ≥90% HPLC

composition

-

mp

196 °C

mp

>300 °C

mp

250-260 °C

mp

-

λmax

531, 314, 295 nm (lit.)

λmax

534, 395, 312 nm (lit.)

λmax

534, 393, 313 nm (lit.)

λmax

546, 403, 338, 307 nm (lit.)


Pictograms

Exclamation mark

Signal Word

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Target Organs

Respiratory system

Storage Class

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

PPE (personal protective equipment)

dust mask type N95 (US), Eyeshields, Faceshields, Gloves



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Questions

1–4 of 4 Questions  
  1. What are the advantages of dye solar cells?

    1 answer
    1. Dye solar cells (DSCs) are 3rd generation solar cells with the promise of high efficiency combined with low production costs.

      Helpful?

  2. What is the Department of Transportation shipping information for this product?

    1 answer
    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

      Helpful?

  3. What can cause degradation of the dye solar cell?

    1 answer
    1. Dye solar cells degrade from ultraviolet radiation.  For this reason, the barrier may include UV stabilizers and/or UV absorbing luminescent chromophores (which emit at longer wavelengths) and antioxidants to protect and improve the effieciency of the cell.

      Helpful?

  4. What are the disadvantages of dye solar cells?

    1 answer
    1. The major disadvantage to the dye solar cell design is the use of a liquid electrolyte, which has temperature stability issues. The electrolyte can freeze at low temperatures and expand at higher temperatures.  It the electrolytes freezes, power production would cease, and it could potentially lead to physical damage.  If the liquid expands at higher temperatures, sealing the panels would be difficult.

      Helpful?

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