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902993

(BPhen)Ni(OAc)2.xH2O

≥95%, powder or crystals

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250 mg

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$128.00
$96.00

About This Item

Empirical Formula (Hill Notation):
C28H22N2NiO4
CAS Number:
2304339-11-3
Molecular Weight:
509.18
MDL number:
MFCD31807324
UNSPSC Code:
12161600
NACRES:
NA.22

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Product Name

(BPhen)Ni(OAc)2.xH2O,

assay

≥95%

form

powder or crystals

reaction suitability

core: nickel, reaction type: Cross Couplings, reagent type: catalyst

mp

>300 °C

SMILES string

O=C(O[Ni]OC(C)=O)C.C1(C2=CC=CC=C2)=CC=NC3=C1C=CC4=C3N=CC=C4C5=CC=CC=C5

InChI

1S/C24H16N2.2C2H4O2.Ni/c1-3-7-17(8-4-1)19-13-15-25-23-21(19)11-12-22-20(14-16-26-24(22)23)18-9-5-2-6-10-18;2*1-2(3)4;/h1-16H;2*1H3,(H,3,4);/q;;;+2/p-2

InChI key

DONATKZVTHVGHJ-UHFFFAOYSA-L

Application

Catalyst for cross couplings via C-N bond activation

Other Notes

Harnessing Alkyl Amines as Electrophiles for Nickel-Catalyzed Cross Couplings via C–N Bond Activation

Disclaimer

Store under N2 atmosphere

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(BPhen)Ni(OAc)2.xH2O

Sigma-Aldrich

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[4,4′-Dimethyl-2,2′-bipyridine]nickel(II) dichloride hydrate ≥95%

Sigma-Aldrich

903019

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(Bathocuproine)NiBr2

Sigma-Aldrich

902985

(Bathocuproine)NiBr2

Chloro(4-cyanophenyl)[(R)-1-[(S)-2-[bis(4-fluorophenyl]phosphino]ferrocenyl]ethyldi-tert-butylphosphine]nickel(II) ≥95%

Sigma-Aldrich

900941

Chloro(4-cyanophenyl)[(R)-1-[(S)-2-[bis(4-fluorophenyl]phosphino]ferrocenyl]ethyldi-tert-butylphosphine]nickel(II)

assay

≥95%

assay

≥95%

assay

-

assay

≥95%

reaction suitability

core: nickel, reagent type: catalyst, reaction type: Cross Couplings

reaction suitability

core: nickel, reaction type: Cross Couplings, reagent type: catalyst

reaction suitability

core: nickel, reaction type: Cross Couplings, reagent type: catalyst

reaction suitability

core: nickel, reaction type: Cross Couplings, reagent type: catalyst

form

powder or crystals

form

powder or crystals

form

powder or crystals

form

powder or solid

mp

>300 °C

mp

>300 °C

mp

>300 °C

mp

-

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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