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For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
208671
Bis(triphenylphosphine)palladium(II) dichloride
98%, solid
Synonym(s):
Dichlorobis(triphenylphosphine)palladium(II), Palladium(II)bis(triphenylphosphine) dichloride, PdCl2(PPh3)2
Select a Size
| Size/SKU | Availability | Price |
|---|---|---|
1 g | Available to ship TODAY | $80.70 |
5 g | Available to ship TODAY | $246.00 |
25 g | Available to ship TODAY | $1,160.00 |
100 g | Available to ship TODAY | $2,560.00 |
About This Item
$80.70
Available to ship TODAYDetails
Product Name
Bis(triphenylphosphine)palladium(II) dichloride, 98%
Quality Segment
assay
98%
form
solid
reaction suitability
core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: inorganic catalyst
SMILES string
Cl[Pd]Cl.c1(P(c2ccccc2)c3ccccc3)ccccc1.c4(P(c5ccccc5)c6ccccc6)ccccc4
InChI
1S/2C18H15P.2ClH.Pd/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2
InChI key
YNHIGQDRGKUECZ-UHFFFAOYSA-L
General description
Application
- Coupling of 2-iodoanisole and terminal alkynes to synthesize 2,3-disubstituted benzofurans.
- Copper-free Sonogashira cross-coupling reaction to synthesize diphenylacetylene.
- Regioselective hydrocarboxylation of styrene.
- Negishi coupling of fluoroarylzinc pivalates to prepare fluorinated oligophenyls.
- Coupling of iodo-α-β-unsaturated esters to afford tetrasubstituted olefins.
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This Item | |||
|---|---|---|---|
| description 98% | description - | description Umicore | description - |
| reaction suitability reaction type: Sonogashira Coupling, reagent type: catalyst, core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Suzuki-Miyaura Coupling, reaction type: Negishi Coupling, reaction type: Stille Coupling, reaction type: Heck Reaction, reaction type: Hiyama Coupling | reaction suitability reaction type: Heck Reaction, reagent type: catalyst | reaction suitability - | reaction suitability reaction type: Stille Coupling, core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Hiyama Coupling, reagent type: catalyst, reaction type: Negishi Coupling, reaction type: Heck Reaction, reaction type: Suzuki-Miyaura Coupling, reaction type: Sonogashira Coupling |
| form solid | form solid | form powder | form solid |
| Quality Level 200 | Quality Level 100 | Quality Level 100 | Quality Level 200 |
| assay 98% | assay - | assay - | assay - |
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Signal Word
Warning
Hazard Codes
Precautionary Statements
Hazard Classifications
Aquatic Chronic 4 - Skin Sens. 1A
Storage Class
11 - Combustible Solids
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
PPE (personal protective equipment)
Eyeshields, Gloves, type N95 (US)
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How can I determine the shelf life / expiration / retest date of this product?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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What is Product 208671, Bis(triphenylphosphine)palladium(II) dichloride soluble in?
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It is soluble in chloroform, toluene, and benzene.
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What is the Department of Transportation shipping information for this product?
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Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.
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Is Product 208671, Dichlorobis(triphenylphosphine)palladium(II), cis or trans?
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We have not specifically tested the material in regards to what isomer it is, however, based on the synthesis of it, it is believed to be predominately trans.
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