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323403

Lithium aluminum hydride

pellets, reagent grade, 95%

Sustainability features

Synonym(s):

LAH, Lithium alanate, Lithium tetrahydroaluminate

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Size/SKUAvailabilityPrice
25 g
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$92.30
100 g
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$213.00

About This Item

Linear Formula:
LiAlH4
CAS Number:
Molecular Weight:
37.95
NACRES:
NA.22
PubChem Substance ID:
EC Number:
240-877-9
MDL number:
UNSPSC Code:
12352306
Assay:
95%
Form:
pellets

$92.30


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grade

reagent grade

Quality Segment

assay

95%

form

pellets

reaction suitability

reagent type: reductant

sustainability

Sustainability features

size

10 mm × 6 mm

mp

125 °C (dec.) (lit.)

greener alternative category

SMILES string

[Li].[AlH3]

InChI

1S/Al.Li.4H/q-1;+1;;;;

InChI key

OCZDCIYGECBNKL-UHFFFAOYSA-N

General description

This product aligns with one or more of the 12 Principles of Green Chemistry Find details here.
Lithium aluminum anhydride is effective as a selective reducing agent.The anhydride may be prepared by reacting lithium hydride with aluminum chloride. It is soluble in ether and it can reduce carboxyl group to primary alcohol group with great ease. Other organic compounds that can be reduced by lithium aluminum hydride are aldehydes, ketones, acid chlorides, acid anhydrides, halides, quinones, nitrogen compounds.

Application

Lithium aluminum hydride (LAH) can be used as a promising material for hydrogen storage applications. Its properties include high gravimetric and volumetric hydrogen densities.
Lithium aluminum hydride can be used to prepare undec-10-en-1-ol, a key intermediate for the preparation of polythioethers.

Physical form

The product may contain up to 20% powder due to mild abrasion of the pellets during packaging and storage.

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686034199877593702
description

pellets, reagent grade, 95%

description

hydrogen-storage grade

description

powder, reagent grade, 95%

description

2.0 M in THF

assay

95%

assay

>99.95%

assay

95%

assay

-

Quality Level

200

Quality Level

100

Quality Level

200

Quality Level

200

reaction suitability

reagent type: reductant

reaction suitability

reagent type: reductant

reaction suitability

reagent type: reductant

reaction suitability

reagent type: reductant

mp

125 °C (dec.) (lit.)

mp

125 °C (dec.) (lit.)

mp

125 °C (dec.) (lit.)

mp

-

form

pellets

form

pellets

form

powder

form

-

greener alternative category

, Enabling

greener alternative category

, Enabling

greener alternative category

Enabling,

greener alternative category

-


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Pictograms

FlameCorrosion

Signal Word

Danger

Hazard Codes

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1A - Water-react. 1

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable



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Questions

1–3 of 3 Questions  
  1. What is the typical size and mass of an individual pellet?

    1 answer
    1. The mass for the 25 G pack size is approximately 24.998 G, the mass for the 100 G pack size is approximately 99.998 G. The size of the pellet is 10 mm × 6 mm (Diameter x Thickness).

      Helpful?

  2. Why should I use Product 323403, the LAH pellets, instead of a fine crystalline powder?

    1 answer
    1. The pellets are recommended for safety reasons. Powdered lithium aluminum hydride can form potentially explosive dust-air mixtures. But use of the lithium aluminum hydride pellets, which can tolerate exposure to air for a short period of time, avoids the dusting associated with the powder. Please note that longer dissolving times, perhaps up to 90 minutes at room temperature, need to be taken into account when using the pellet form.

      Helpful?

  3. What is the Department of Transportation shipping information for this product?

    1 answer
    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

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