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324124

2-Chloro-1,3,2-benzodioxaphosphorin-4-one

95%, solid

Synonym(s):

SalPCl, Salicyl chlorophosphite

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Size/SKUAvailabilityPrice
5 g
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$149.00
25 g

Available to ship TODAYfromMILWAUKEE

$377.00
$282.75

About This Item

Empirical Formula (Hill Notation):
C7H4ClO3P
CAS Number:
Molecular Weight:
202.53
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
Beilstein/REAXYS Number:
1311951

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Product Name

2-Chloro-1,3,2-benzodioxaphosphorin-4-one, 95%

Quality Segment

assay

95%

form

solid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand

bp

127-128 °C/11 mmHg (lit.)

mp

36-40 °C (lit.)

functional group

phosphine

storage temp.

2-8°C

SMILES string

ClP1OC(=O)c2ccccc2O1

InChI

1S/C7H4ClO3P/c8-12-10-6-4-2-1-3-5(6)7(9)11-12/h1-4H

InChI key

BVOITXUNGDUXRW-UHFFFAOYSA-N

Application

2-Chloro-1,3,2-benzodioxaphosphorin-4-one is used as a reagent:
  • In the phosphorylation and phosphitylation of alcohols.
  • In the formation of H-phosphonates which are commonly utilized in the synthesis of nucleotides.
  • To synthesize nucleoside triphosphates by treating with acyl protected nucleoside.


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description

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assay

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assay

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assay

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reaction suitability

reaction type: Heck Reaction, reagent type: ligand, reaction type: Hiyama Coupling, reaction type: Stille Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Suzuki-Miyaura Coupling, reaction type: Sonogashira Coupling, reaction type: Negishi Coupling

reaction suitability

reaction type: Heck Reaction, reaction type: Hiyama Coupling, reagent type: ligand, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: Negishi Coupling

reaction suitability

reagent type: ligand, reaction type: Negishi Coupling, reaction type: Stille Coupling, reaction type: Sonogashira Coupling, reaction type: Heck Reaction, reaction type: Suzuki-Miyaura Coupling, reaction type: Hiyama Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction

reaction suitability

-

form

solid

form

-

form

liquid

form

solid

functional group

phosphine

functional group

-

functional group

-

functional group

phenyl

Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

100

storage temp.

2-8°C

storage temp.

-

storage temp.

2-8°C

storage temp.

-


Pictograms

Corrosion

Signal Word

Danger

Hazard Codes

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

supp_hazards

Storage Class

8A - Combustible corrosive hazardous materials

Flash Point (°F)

235.4 °F - closed cup

Flash Point (°C)

113 °C - closed cup

PPE (personal protective equipment)

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges



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