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345482

Methyl (R)-(+)-2,2-dimethyl-1,3-dioxolane-4-carboxylate

98%

Synonym(s):

α,β-Isopropylidene-D-glyceric acid methyl ester, Methyl α,β-isopropylidene-D-glycerate, Methyl 2,3-O-isopropylidene-D-glycerate

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Size/SKUAvailabilityPrice
5 g
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$149.00

About This Item

Empirical Formula (Hill Notation):
C7H12O4
CAS Number:
Molecular Weight:
160.17
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
4292353
Assay:
98%
Form:
liquid

$149.00


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Quality Segment

assay

98%

form

liquid

optical activity

[α]20/D +8.5°, c = 1.5 in acetone

refractive index

n20/D 1.426 (lit.)

bp

70-75 °C/10 mmHg (lit.)

density

1.106 g/mL at 25 °C (lit.)

functional group

ester, ether, ketal

SMILES string

COC(=O)[C@H]1COC(C)(C)O1

InChI

1S/C7H12O4/c1-7(2)10-4-5(11-7)6(8)9-3/h5H,4H2,1-3H3/t5-/m1/s1

InChI key

DOWWCCDWPKGNGX-RXMQYKEDSA-N

Application

Methyl (R)-(+)-2,2-dimethyl-1,3-dioxolane-4-carboxylate may be used as a starting material to synthesize (2R)-[1-2H2]-glycerol, a probe to study the stereochemistry of glycerol metabolism in Streptomyces cattleya. It may also be used to synthesize organic building blocks like (R)-2,3-dihydroxy-3-methylbutyl toluene-p-sulfonate and (2S,8R)-2-amino-8-[(R) 2,2-dimethyl-1,3-dioxolan-4-yl]-8-oxooctanoic acid.

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This Item
254606D126306237744
description

98%

description

96%

description

97%

description

98%, optical purity ee: 99% (GLC)

assay

98%

assay

96%

assay

97%

assay

98%

Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

200

form

liquid

form

liquid

form

liquid

form

liquid

density

1.106 g/mL at 25 °C (lit.)

density

1.106 g/mL at 25 °C (lit.)

density

1.143 g/mL at 25 °C (lit.)

density

1.07 g/mL at 25 °C (lit.)

bp

70-75 °C/10 mmHg (lit.)

bp

84-86 °C/15 mmHg (lit.)

bp

117 °C/0.015 mmHg (lit.)

bp

82-83 °C/14 mmHg (lit.)

refractive index

n20/D 1.426 (lit.)

refractive index

n20/D 1.425 (lit.)

refractive index

n20/D 1.466 (lit.)

refractive index

n20/D 1.434 (lit.)


Storage Class

10 - Combustible liquids

WGK

WGK 3

Flash Point (°F)

167.0 °F - closed cup

Flash Point (°C)

75 °C - closed cup

PPE (personal protective equipment)

Eyeshields, Gloves, type ABEK (EN14387) respirator filter



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