368199
(S)-(−)-α,α-Diphenyl-2-pyrrolidinemethanol
99%
Synonym(s):
(S)-(−)-2-(Diphenylhydroxymethyl)pyrrolidine, α,α-Diphenyl-L-prolinol
Select a Size
| Size/SKU | Availability | Price |
|---|---|---|
1 g | Check Cart for Availability | $30.40 |
5 g | Check Cart for Availability | $106.00 |
About This Item
$30.40
Quality Segment
assay
99%
form
solid
optical activity
[α]20/D −67°, c = 3 in chloroform
reaction suitability
reagent type: chrial catalyst
mp
77-80 °C (lit.)
functional group
hydroxyl, phenyl
SMILES string
OC([C@@H]1CCCN1)(c2ccccc2)c3ccccc3
InChI
1S/C17H19NO/c19-17(16-12-7-13-18-16,14-8-3-1-4-9-14)15-10-5-2-6-11-15/h1-6,8-11,16,18-19H,7,12-13H2/t16-/m0/s1
InChI key
OGCGXUGBDJGFFY-INIZCTEOSA-N
Application
- DPPM reacts with catecholborane to form a spiroborate ester, which can be an efficient catalyst for the synthesis of enantiopure alcohols by borane reduction of acetophenone.
- The catalyst generated in situ by reacting DPPM with borane-diethylaniline, can efficiently catalyze the enantioselective reduction of 2′-fluoroacetophenone.
- Mesoporous SBA-15 silica functionalized with DPPM can catalyze the addition of diethylzinc to benzaldehyde to form (S)-1-phenyl-propanol.
1 of 1
This Item | |||
|---|---|---|---|
| description 99% | description 97% | description 99% | description 97% |
| reaction suitability reagent type: organic catalyst | reaction suitability - | reaction suitability - | reaction suitability reagent type: organic catalyst |
| assay 99% | assay 97% | assay 99% | assay 97% |
| form solid | form - | form - | form powder |
| functional group hydroxyl, phenyl | functional group hydroxyl | functional group hydroxyl | functional group hydroxyl |
| Quality Level 200 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
| optical activity [α]20/D −67°, c = 3 in chloroform | optical activity [α]20/D +31°, c = 1 in toluene | optical activity [α]20/D −31°, c = 1 in toluene | optical activity [α]22/D -98.0°, c = 1 in methanol |
Signal Word
Warning
Hazard Codes
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
PPE (personal protective equipment)
dust mask type N95 (US), Eyeshields, Gloves
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